Фазовые равновесия в системе MnTе–MnGa2Te4–MnIn2Te4
Аннотация
Семейство соединений с общей формулой АВ2Х4 (А – Mn, Fe, Co, Ni; B – Ga, In, Sb, Bi; X – S, Se, Te) и сложные фазы переменного состава на их основе относятся к перспективным функциональным материалам, проявляющим термоэлектрические, фотоэлектрические, оптические и магнитные свойства. В данной работе продолжено исследование многокомпонентных систем на основе халькогенидов переходных металлов и представлены результаты исследования фазовых равновесий в системе MnTе–MnGa2Te4–MnIn2Te4 методами дифференциального термического и рентгенофазового анализа.
На основании экспериментальных результатов построены политермические сечения MnTe–MnGaInTe4 и MnGa2Te4–[A] ([A] – двухфазный сплав боковой системы 2MnTe–MnIn2Te4 состава 50 мол. % MnIn2Te4), изотермическое сечение при 800 K фазовой диаграммы и проекция поверхности ликвидуса. Установлено, что ликвидус состоит из полей первичной кристаллизации 4 фаз: 1 – Mn-ht; 2 – фазы на основе различных модификаций MnTe; 3 – g 1 ; 4 – g2.Определены типы и координаты нон- и моновариантных равновесий.
На основе тройных (MnGa2Te4, MnIn2Te4) соединений выявлены широкие области твердых растворов, представляющие интерес как магнитные материалы
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