A novel method for determining the adsorbed phase volume from an excess adsorption isotherm for an arbitrary adsorbent
Keywords:
adsorption volume, excess adsorption, absolute adsorption.
Abstract
Adsorption volume is an important parameter for characterizing the adsorbent–adsorbate system. In this paper the new method for reliable evaluation of adsorption volume is presented. The validity of the proposed method is tested by 11 experimentally studied systems. The test results indicate that the method has strong potential for practical use.
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References
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2.Murata K., Kaneko K., Chem. Phys. Lett., 2000, Vol. 321, pp. 342-348.
3.Murata K., El-Merraoui M., Kaneko K., J. Chem. Phys., 2001, Vol. 114, pp. 4196-4205
4.Keller J.U., Zimmermann W., Schein E., Adsorption, 2003, Vol. 9, pp. 177-188.
5.Jakubov T.S., Jakubov E.S., Kolloid. zhurn., 2007, Vol. 69, No 5, pp. 709-713.
6.Jakubov E.S., Jakubov T.S., Larionov O.G., Kolloid. zhurn., 2007, Vol. 69, No 5. pp. 714-717.
7.Gruszkiewicz M.S., Rother G., Wesolowski D.J., Cole D.R. et al., Langmuir, 2012, Vol. 28, pp. 5070-5078.
8.Myers A.L., Monson P.A., Adsorption, 2014, Vol. 20, pp. 591-622.
9.Phadungbut P., Fan C., Do D.D., Nicholson D. et al., Colloids and Surfaces A:
Physicochem. Eng. Aspects, 2015, Vol. 480, pp. 19-27.
10.Shekhovtsova L.G., Yakubov T.S., Izv. AN. Ser. Khim., 1995, Vol. 44, pp. 431-433.
11.Zhou L., Zhou Y., Bai S., Lü C. et al., J. Colloid Interface Sci., 2001, Vol. 239, pp. 3338.
12.Gumma S., Talu O., Adsorption, 2003, Vol. 9, pp. 17-28.
13.Gumma S., Talu O., Langmuir, 2010, Vol. 26, pp. 17013-17023.
14.Hill T.L. Theory of physical adsorption. In: Frankenburg W.G., Komarewsky V.I., Rideal E.K., eds., Adv. Catal., 1952, Vol. 4, pp. 211-258.
15.Serpinskii V.V., Yakubov T.S., Izv. AN SSSR. Ser. Khim. 1985. Vol. 34, No 1. pp. 6-11.
16.Malbrunot P., Vidal D., Vermesse J., Chahine R. et al.., Langmuir, 1992, Vol. 8, pp. 577-580.
17.Vidal D., Malbrunot P., Guengant L., Vermesse J., Bose T.K. et al. Rev. Sci. Instrum., 1990, Vol. 61, pp. 1314-1318.
18.Herbst A., Harting P., Adsorption, 2002, Vol. 8, pp. 111-123.
19.Pribylov A.A., Stoeckli H.F., Zhurn. fiz. Khimii, 1998, Vol. 72, pp. 306-312.
20.Pribylov A.A., Serpinsky V.V., Kalashnikov S.M., Zeolites, 1991, Vol. 11, pp. 846-849.
21.Sudibandriyo M., Pan Z., Fitzgerald J.E., Robinson R.L. et al., Langmuir, 2003, Vol. 19, pp. 5323-5331.
22. Pribylov A.A. and Jakubov T.S., Izv. AN. Ser. khim., 1996, Vol.45, No 5, pp. 1078-1082.
23.Breck D.W. Zeolite molecular sieves. Structure, chemistry, and use. John Wiley & Sons, Inc., New York, 1974. 771 p.
Published
2019-11-14
How to Cite
Jakubov, E. S. (2019). A novel method for determining the adsorbed phase volume from an excess adsorption isotherm for an arbitrary adsorbent. Sorbtsionnye I Khromatograficheskie Protsessy, 16(2). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/1334
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Статьи
