Sorption by the polymeric sorbents based on crosslinked polystyrene
Abstract
The influence of the polymer matrix nature on the sorption properties of some cross-linked polyelectrolytes is analyzed. It is shown that the nature of the polymeric sorbents selectivity is associated with heterophase polymer gel structure. The effect of the amount of crosslinking agent, nature of polar groups and individual properties of some low molecular weight electrolytes on the selectivity of the sorbents are studied. It was shown that the obtained values of the distribution constants do not change their values when varying the concentration and composition of the solution. This property of polymeric sorbents may be used to separate solutes.
Downloads
References
2.Mauritz K.A., Hopfinger A.J., Modern Aspects Electrochem, 1982, Vol. 14, pp. 425.
3.Ferapontov N.B., Tokmachev M.G. and Gagarin A.N., Russian Journal of Physical Chemistry A, 2009, Vol. 83, No 8, pp. 13211325.
4.Koryta I., Iony, elektrony, membrany, M., Mir, 1983, 270 p.
5.Shchukin E.D., Pertsov A.V., Amelina E.A., Kolloidnaya khimiya, M., Vysshaya shkola, 2004, 445 p.
6.Ferapontov N.B. et al., Reactive & Functional Polymers, 2000, Vol. 45, pp. 145153.
7.Mikulin G.I., Voznesenskaya I.E., Sb. statei Pod red. G.I. Mikulina, L., Khimiya, 1968, pp. 304-329.
8.Hatch M.J., Dillon J.A., I&EC Process Design and Development, 1963, Vol. 2, No 4, pp. 253-263.
9.Götzelmann W., Hartinger L., Gülbas M., Metalloberfläche, 1987, Vol. 41, No 5, pp.208212.
10.Ferapontov N.B., Gorshkov V.I., Trobov Kh.T., Parbuzina L.R. Patent RF № 2056899, 1996.
11.Gruzdeva A.N., Khamizov R.Kh, Zolotarev P.P., Protection of Metals and Physical Chemistry of Surfaces, 2015, Vol.51, No 6, pp.929-933.