About chromatographic behavior of flavonoids in reversed-phase HPLC

  • Ludmila A. Deineka Ph.D., Professor assistant of Common Chemistry Chair of Institute of Engineering Technologies and Natural Sciences of Belgorod National Research University, Belgorod
  • Victor I. Deineka Dr. Sci.(Chemistry) Prof., Common Chemistry Chair of Institute of Engineering Technologies and Natural Sciences of Belgorod National Research University, Belgorod, e-mail: deineka@bsu.edu.ru
  • Irena P. Blinova Dr. Sci.(Chemistry) Professor assistant of Common Chemistry Chair of Institute of Engineering Technologies and Natural Sciences of Belgorod National Research University, Belgorod
  • Michael O. Kostenko undergraduate of Institute of Engineering Technologies and Natural Sciences of Belgorod National Research University, Belgorod
  • Elena Yu. Oleinitz Syudent of Institute of Engineering Technologies and Natural Sciences of Belgorod National Research University, Belgorod
Keywords: flavonoids, retention, particularities, reversed-phase HPLC, separation map, effectivity map.

Abstract

It has been shown that particularities of different flavonoids retention in reversed-phase HPLC caused by basic structure alteration or by introduction (or withdrawal) of functional groups may be revealed by separation map analysis constructed by relative retention analysis method. It has been proposed that the particularities are connected with no identical sorption mechanisms because of the molecule steric structure differences; the phenomenon may be detected by analysis of the chromatographic effectivity map.

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References

1 Héberger K., J. Chromatogr. A, 2007, Vol.
1158, pp. 273-305. 2 Deineka V.I., Russ. J. Phys. Chem., 2006,
Vol. 80, pp. 429-434.
3.
Karpov S.I., Matveeva M.V., Selemenev V.F., Russian Journal of physical Chemisnry A, 2001, Vol. 75,No 2, pp. 266-271.
4.
Daigle D.J., Conkerton E.J., J. Chromatogr,. 1982, Vol. 240, рр. 202-205.
5.
Voskobojnikova I.V. et al., Farmaciya, 1992, No 6, pp. 74-75.
6.
Hramova E.P., Materialy VII Conf. «Analitika Sibiri I Dalnego Vostoka – 2004», p. 154
7.
Evsevleeva L.G., Dobrynina N.N., Bykova L.M., Izv. Vysshih Uchebnyh Zavedenij. Ser. Himiya i Himicheskaya Tekhnologiya, 2009, Vol. 52, No 11, pp. 42-45
8.
Deineka V.I., Zhurnal Fizicheskoj Himii, 2004, Vol. 78, pp. 144-147.
9.
Deineka V.I., Deineka L.A., Saenko I.I., Chulkov A.N., Russ. J. Phys. Chem., 2015, Vol. 89, pp. 1172-1177
Published
2019-11-15
How to Cite
Deineka, L. A., Deineka, V. I., Blinova, I. P., Kostenko, M. O., & Oleinitz, E. Y. (2019). About chromatographic behavior of flavonoids in reversed-phase HPLC. Sorbtsionnye I Khromatograficheskie Protsessy, 16(3). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/1361