Preparation, properties and application of the colloid solutions of nano-sized ion-exchangers

  • Anatoly M. Dolgonosov Dr.Sci.(Chem.), Leading scientific associate, Lab of Sorption Methods, GEOKHI RAS, Prof. of Chemistry Chair, University “Dubna”, Moscow, amdolgo@mail.ru
  • Ruslan Kh. Khamizov Dr.Sci.(Chem.), Chief of Lab of Sorption Methods, GEOKHI RAS, Moscow
  • Nadezhda K. Kolotilina Scientific associate, Lab of Sorption Methods, GEOKHI RAS, Moscow
  • Svetlana U. Shaikhina Research engineer, Lab of Sorption Methods, GEOKHI RAS, Moscow
  • Polina V. Evstigneeva Bachelor, University “Dubna”, Lab of Sorption Methods, GEOKHI RAS, Moscow
Keywords: nano-sized polymeric ion exchangers, solid-phase ion exchange, ion chromatography, luminescence, drug delivery.

Abstract

Polymeric resins as the nano-sized particles, i.e., nano-ion-exchangers, are the unusual objects - both hyper-charged ions and the ion exchangers, forming stable aqueous suspensions. The paper deals with the theoretical and practical study of the properties of nano-exchangers and methods for their preparation. Selected examples of such objects and the prospects of their application in analytical chemistry and medicine are presented. The results are given for dynamic experiments in course of which the sorption of nanoexchangers and the ions of related solutions are carried out, and the standard state nano-suspensions are created. The feature of kinetics on nano-sized resins is the extremely fast mass-transfer, which allows carrying out the process of the solid-state exchange of counter ions between the exchanging phases of same polarity.

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References

1.
Turner S.R., Weiss R.A., Lundberg R.D., J. Polym. Sci. Polym. Chem. Ed., 1985, Vol. 23, pp. 535-540.
2.
Brijmohan S.B., Swier S., Weiss R.A., Shaw M.T., Ind. Eng. Chem. Res., 2005, Vol. 44, pp. 8039-8045.
3.
Dolgonosov A.M., Kolotilina N.K., Yadykov M.C. Patent RF, № 2499628, 2013.
4. Tobolov A.A., Bogatyrev V.L., Zhurko
F.V. // Vtoroi vsesoyuznyi simpozium po termodinamike ionnogo obmena. Extended abstracts, 1975, Minsk, pp. 50-53.
5.
Liu X., Pohl C., Woodruff A., Chen J., J. Chromatogr. A, 2011, Vol. 1218, pp. 34073412.
6.
Small H., Stevens T., Bauman W., Anal. Chem., 1975, Vol. 47, No 11, pp.1801-1809.
7.
Sarzanini C., J. Chromatogr. A, 2002, Vol. 956, pp. 3-15.
8.
Dolgonosov A.M., Khamizov R.Kh., IEX2012. Electronic book / Novel Extractants -Dolgonosov et al. Bipolar nano-surface for high-performance ion exchange separation.
9.
Dolgonosov A.M., Kolotilina N.K., Yadykov M.C., Burmistrov A.A., J. Anal. Chem., 2013, Vol. 68, No 5, pp. 444-449.
10.Problemy analiticheskoi khimii. Vol.19. Luminestsentnyi analiz / Ed. G.I. Romanovskaya, M., Nauka, 2015, 285 p.
11.Starostin K.M. . et al, Vestnik Rossiiskogo gosudarstvennogo meditsinskogo universiteta, 2015, No 4, pp. 58-64.
Published
2019-11-15
How to Cite
Dolgonosov, A. M., Khamizov, R. K., Kolotilina, N. K., Shaikhina, S. U., & Evstigneeva, P. V. (2019). Preparation, properties and application of the colloid solutions of nano-sized ion-exchangers. Sorbtsionnye I Khromatograficheskie Protsessy, 16(4). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/1364