New model of multicomponent mass transfer kinetics and concentration waves in bifunctional matrix of nanocomposites
Keywords:
nanocomposites (NC), mass transfer, concentration waves, diffusion, multicomponent kinetics, bi-functional matrix, active nanosites.
Abstract
The theoretical investigation is presented with the aim of modeling of the multicomponent mass
transfer process in the NanoComposites (NC) - novel materials with the bifunctional matrix. The NC
Model for the multicomponent mass transfer in the bi-functional NC matrix includes into the
consideration the proposed key conception: two co-existing routes (I - chemical reactions onto the active
NC centers-sites, and II - diffusion mass transfer, I +II) inside the bi-functional NC matrix. All the results
are presented in the terms of the additional W+-concept: propagating multi-component concentration
waves in the NC matrix. The results of the calculations for the multicomponent concentration wavesdistributions
are new and may be illustrated by author’s calculating animations.
Downloads
Download data is not yet available.
References
1. Kaлиничев A. Кинетические и динамические хроматографические системы и модель
массопереноса: Поведение многокомпонентных концентрационных волн.//Защита
Металлов и Физическая Химия Поверхностей. 2011. Т. 47, N6. С. 570-579.
2. Kalinitchev A. Mass Transfer Kinetics Modelling in Bifunctional Ion Exchangers with
Chemical Reactions on Active Centers. in: “IEX 2012” El. Book, S. Fundamentals. M. Cox
(Ed.), Soc. Chem. Ind., Lond. 2012. С.1-18.
3. Kalinitchev A. Multicomponent Mass Transfer Kinetics in the Model of NanoComposites
with Bifunctional Matrix// Smart NanoComposites. Nova Sci. Publ., Ed. (in Chief.): K. Levine.
- 2013.V.3, N2. С.1-18. (сайт:http://www.novapublishers.com/catalog/product_info.
php?products_id=40111).
4. Kalinitchev A. New Kinetic сomputerized Model for Multicomponen Mass Transfer in
Bifunctional Matrix of Nanocomposites // Advances in Nanoparticles.
ANP.Sci.Res.Publ.:SCIRP. E-Journal., -2013. V.2, N2. P.1-18. (сайт ANP:
http://www.scirp.org/journal/anp/).
5. Кравченко T., Полянский Л., Калиничев А., Конев Д. Нанокомпозиты Металл-
Ионообменник. M.: Наука, 2009. 390с.
6. Hwang Y-I. and Helfferich F. Generalized model for multispecies IEx kinetics including
fast chemical reactions //Reactive Polymers, 1987.V.5, P. 237-252.
7. Kalinitchev A.I. Investigation of intraparticle IEx kinetics in selective systems, in (eds.: Ja.
Marinsky & Y. Marcus) IEx & Solv. Extr., M.Dekker, 1995.V.12. Ch.4: P. 149-196.
8. Helfferich F. Ion Exchange Kinetics. Ch.5, in: Ion Exchange (A series of Adv.) Ja.I.
Marinsky (Ed.). St. Univ. NY. at Buffalo 1966. P. 1 -13.
9. Helfferich F. IEx Kinetics – Evolution of a Theory. in: “Mass Transfer & Kinetics of IEx”.
L. Liberti&F. Helfferich (Eds.). M.Sijthoff & Nordhoff . The Hague. 1983. P. 157-179.
10. Helfferich F. and Klein G. Multicomponent Chromatography. Theory of Interference,
New York: M. Dekker Inc. 1970. 360P.
11. Industrial & Engineering Chemistry Research. J. (prof. F. Helfferich Festschrift)//Am.
Chem. Soc. J. 1995.V.34. N8. P. 2551-2922.
12. Калиничев А. И. Нелинейная Теория многокомпонентной динамики сорбции и
хроматографии. // Успехи Химии. 1996.Т.65. С. 95-115.
13. Kalinitchev A. and Hoell W. Multi-component IEx dynamics with the equilibria
described by surface complexation theory, in: “IEX2004, Ion Exchange Technology for Today
and Tomorrow”, M. Cox (Ed.), Soc. Chem. Ind., London, 2004. P. 53-58.
14. Kalinitchev A. and Hoell W. Theoretical principles of multicomponent frontal and
displacement elution chromatography on the basis of SCT theory, in IEX 2008, Recent
Advances in IEx Theory&Practice, M. Cox (Ed.), Soc. Chem. Ind., London, 2008. P. 85-93.
15.Долгоносов А.М., Хамизов Р.Х., Крачак А.Н., Прудковский А.Г. Макроскопическая
модель многокомпонентной ионообменной кинетики// ДАН 1995.Т.342,N1. C.53-60.
(Macroscopic model for multispecies IEx kinetics. // React. Func. Polym. 1995.V.28. P.13-20.)
массопереноса: Поведение многокомпонентных концентрационных волн.//Защита
Металлов и Физическая Химия Поверхностей. 2011. Т. 47, N6. С. 570-579.
2. Kalinitchev A. Mass Transfer Kinetics Modelling in Bifunctional Ion Exchangers with
Chemical Reactions on Active Centers. in: “IEX 2012” El. Book, S. Fundamentals. M. Cox
(Ed.), Soc. Chem. Ind., Lond. 2012. С.1-18.
3. Kalinitchev A. Multicomponent Mass Transfer Kinetics in the Model of NanoComposites
with Bifunctional Matrix// Smart NanoComposites. Nova Sci. Publ., Ed. (in Chief.): K. Levine.
- 2013.V.3, N2. С.1-18. (сайт:http://www.novapublishers.com/catalog/product_info.
php?products_id=40111).
4. Kalinitchev A. New Kinetic сomputerized Model for Multicomponen Mass Transfer in
Bifunctional Matrix of Nanocomposites // Advances in Nanoparticles.
ANP.Sci.Res.Publ.:SCIRP. E-Journal., -2013. V.2, N2. P.1-18. (сайт ANP:
http://www.scirp.org/journal/anp/).
5. Кравченко T., Полянский Л., Калиничев А., Конев Д. Нанокомпозиты Металл-
Ионообменник. M.: Наука, 2009. 390с.
6. Hwang Y-I. and Helfferich F. Generalized model for multispecies IEx kinetics including
fast chemical reactions //Reactive Polymers, 1987.V.5, P. 237-252.
7. Kalinitchev A.I. Investigation of intraparticle IEx kinetics in selective systems, in (eds.: Ja.
Marinsky & Y. Marcus) IEx & Solv. Extr., M.Dekker, 1995.V.12. Ch.4: P. 149-196.
8. Helfferich F. Ion Exchange Kinetics. Ch.5, in: Ion Exchange (A series of Adv.) Ja.I.
Marinsky (Ed.). St. Univ. NY. at Buffalo 1966. P. 1 -13.
9. Helfferich F. IEx Kinetics – Evolution of a Theory. in: “Mass Transfer & Kinetics of IEx”.
L. Liberti&F. Helfferich (Eds.). M.Sijthoff & Nordhoff . The Hague. 1983. P. 157-179.
10. Helfferich F. and Klein G. Multicomponent Chromatography. Theory of Interference,
New York: M. Dekker Inc. 1970. 360P.
11. Industrial & Engineering Chemistry Research. J. (prof. F. Helfferich Festschrift)//Am.
Chem. Soc. J. 1995.V.34. N8. P. 2551-2922.
12. Калиничев А. И. Нелинейная Теория многокомпонентной динамики сорбции и
хроматографии. // Успехи Химии. 1996.Т.65. С. 95-115.
13. Kalinitchev A. and Hoell W. Multi-component IEx dynamics with the equilibria
described by surface complexation theory, in: “IEX2004, Ion Exchange Technology for Today
and Tomorrow”, M. Cox (Ed.), Soc. Chem. Ind., London, 2004. P. 53-58.
14. Kalinitchev A. and Hoell W. Theoretical principles of multicomponent frontal and
displacement elution chromatography on the basis of SCT theory, in IEX 2008, Recent
Advances in IEx Theory&Practice, M. Cox (Ed.), Soc. Chem. Ind., London, 2008. P. 85-93.
15.Долгоносов А.М., Хамизов Р.Х., Крачак А.Н., Прудковский А.Г. Макроскопическая
модель многокомпонентной ионообменной кинетики// ДАН 1995.Т.342,N1. C.53-60.
(Macroscopic model for multispecies IEx kinetics. // React. Func. Polym. 1995.V.28. P.13-20.)
Published
2019-11-21
How to Cite
Kalinitchev, A. I. (2019). New model of multicomponent mass transfer kinetics and concentration waves in bifunctional matrix of nanocomposites. Sorbtsionnye I Khromatograficheskie Protsessy, 13(4). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/1659
Section
Статьи
