The influence of surface chemistry of carbon black on adsorption of oligobutadienes rubber
Keywords:
liquid phase adsorption, synthetic rubber, carbon black
Abstract
In this work we have studied the adsorption of oligobutadiene rubber (synthetic rubber) on native
carbon black in comparison to heat-treated samples. Statical (batch) method has been used to determine isotherms
of adsorption. Experimental error was less then 3%. We found that thermal treatment of native carbon
black increases adsorption of synthetic rubber from diluted n-heptane solution. Obtained isotherms of adsorption
allow us to calculate distribution coefficients and differential Helmholtz energy for studied systems. In
comparison to native carbon black, heat-treated samples showed the higher adsorption performance due to
specific interactions at the solid-liquid interface.
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References
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3. Donnet J.B., Vidal A., Chapter: Carbon black: Surface properties and interactions with elastomers. Pharmacy, Thermomechanics, Elastomers, Telechelics, Berlin, Heidelberg, New York, Tokyo: Spriger-Verlag, 2006, pp. 103-127.
4. J. M. D. Tascon, Novel Carbon Adsorbents, Elsevier, 2012, 686 p.
5. Kiselev A.V., Intermolecular interactions in adsorption and chromatography. M.: Higher School, 1986, 360 p.
6. Lipatov Yu.S. Physico-chemical bases of filling of polymers, M., Chemistry, 1991, 259 p.
7. Eltekova N.A., Eltekov Y.A., Carbon, 1993, Vol. 31, pp. 957-961.
8. Eltekova N.A., Razdyakonona G.I., Eltekov Y.A., Pure Appl. Chem., 1993, Vol. 65, pp. 2217-2221.
9. Eltekova N.A., Berek D., Novak.I., Belliardo F, Carbon, 2000, Vol. 38, pp. 373-377.
10. Boehm H.P., Carbon, 1994. Vol. 32, pp. 757-1032.
11. Zhang Yimin, Ge S., Tang B. et al., Macromol., 2001, Vol. 34, pp. 7056-7065.
12. Zaborski M., Donnet J.B., Macromol. Symp., 2003, Vol. 194(1), pp. 87-100.
13. Maafa D., Balard H., Donnet J.B., Rubber Chem. Technol., 2007, Vol. 80(5), pp. 895-906.
14. Eltekov A.Y., Eltekova N.A., Roldugin V.I., Colloid J., 2007, Vol. 69, pp. 248-251.
15. Eltekova N.A., Sokolova N.P., Gorbunov A.M., Eltekov A.Y., Phys. Chem. Surf. Protect. Mat., 2013. Vol. 49, pp. 421-425.
16. Kiselev A.V., Malygin Yu.V., Stroev V. N., Eltekov Yu.A., Kolloidn. Zurn., 1982, Vol. 44, pp. 1051-1056.
17. Likholobov V.A., Pyanova L.G., Baklanova O.N., Sedanova A.V., Solid fuel chem., 2014, Vol. 48, pp. 382-391.
18. Surovikin Y.V., Shaitanov A.G., Drozdov V.A., Rezanov I.V. et a., Solid fuel chem., 2014, Vol. 48, pp. 392-403.
19. Shilov A.D. Basov B.K., Eltekov Yu.A., Polymer Sci. U.S.S.R., 1982. Vol. 24. pp. 728-731.
20. Boehm H.P., Carbon, 2002, Vol. 40, pp. 145-149.
21. Eltekova N.A., Eltekov Yu.A., Rus. J. Phys.Chem., 2005, Vol. 79, pp. 620-623.
22. Eltekova N.A., Eltekov Yu.A., Rus. J. Phys. Chem., 2007, Vol. 81, pp. 602-606.
23. Eltekov A.Y., Eltekova N.A., Eltekov Y.A., Sorbtsionnye I khromatograficheskie protsessy, 2014, Vol. 14, No 6, pp. 977-987.
24. Eltekov A.Yu., Sorbtsionnye I khromatograficheskie protsessy, 2015, Vol. 15, No 3, pp. 456-463.
Published
2018-02-21
How to Cite
Эльтекова, Н. А., Эльтеков, А. Ю., & Эльтеков, Ю. А. (2018). The influence of surface chemistry of carbon black on adsorption of oligobutadienes rubber. Sorbtsionnye I Khromatograficheskie Protsessy, 17(2), 264-271. https://doi.org/10.17308/sorpchrom.2017.17/379
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