Хемосорбция водорода на оксидах металлов с добавками оксида палладия (II
Аннотация
Хемосорбция может привести к изменению электропроводности, что позволяет применять полупроводниковые материалы для создания газовых сенсоров. С другой стороны, полупроводниковые сенсоры могут быть использованы как устройства для исследования хемосорбции газов. В данной работе было поставлено две задачи. Первая из них – создание сенсора для селективного определения водорода в воздухе, в том числе, в смеси с другими газами. Вторая задача – определение механизма хемосорбции водорода на поверхности оксидов металлов с добавками оксида палладия (II).
Получены и охарактеризованы нанодисперсные материалы на основе SnO2 и WO3 с добавками 3 % PdO по массе. Проведено сравнение электрофизических характеристик этих материалов в стационарных температурных режимах, а также при температурной модуляции в присутствии водорода, метана и их смесей. Определены особенности хемосорбции водорода на поверхности металлоксидных полупроводников на основе SnO2 и WO3 с добавками PdO в режиме температурной модуляции сенсора. Показано, что экстремумы на зависимости электропроводности сенсора от температуры можно объяснить вкладом переноса протонов в общую электрическую проводимость.
Наличие экстремумов электропроводности сенсоров, которые наблюдаются в режиме термомодуляции в присутствии водорода, позволяет проводить качественный и количественный анализ не только однокомпонентных газовых систем, но также смесей водорода с другими газами-аналитами. В частности, в данной работе была показана возможность определения состава смеси водород-метан в воздухе с помощью единичного металлоксидного сенсора. Преимуществом данного подхода является простота обработки массивов многомерных данных.
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Литература
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