Up-conversion luminescence in mixed crystals BaY1.8Lu0.2F8 doped with Er3+ ions excited at 1532 nm.

Alexey S. Nizamutdinov; Sergey V. Gushchin; Sergey A. Bukarev; Alexey A. Shavelev; Mikhail A. Marisov; Ainur A. Shakirov; Airat G. Kiiamov; Anna V.  Astrakhantseva; Andrey A. Lyapin

doi:10.17308/kcmf.2022.24/10256

Authors

Alexey S. Nizamutdinov Kazan Federal University, 18 Kremlevskaja str., Kazan 420008, Russian Federation https://orcid.org/0000-0003-1559-6671 (unauthenticated)
Sergey V. Gushchin National Research Mordovia State University, 68 Bolshevitskaya str., Saransk 430005, Russia https://orcid.org/0000-0003-1680-337X (unauthenticated)
Sergey A. Bukarev National Research Mordovia State University, 68 Bolshevitskaya str., Saransk 430005, Russia https://orcid.org/0000-0003-2781-5974 (unauthenticated)
Alexey A. Shavelev Kazan Federal University, 18 Kremlevskaja str., Kazan 420008, Russian Federation https://orcid.org/0000-0001-5700-6989 (unauthenticated)
Mikhail A. Marisov Kazan Federal University, 18 Kremlevskaja str., Kazan 420008, Russian Federatio; Zavoisky Physical-Technical Institute, FRC Kazan Scientific Center of the Russian Academy of Sciences, 10/7 Sibirsky av., Kazan 420029, Russian Federation https://orcid.org/0000-0001-8425-7046 (unauthenticated)
Ainur A. Shakirov Kazan Federal University, 18 Kremlevskaja str., Kazan 420008, Russian Federation https://orcid.org/0000-0002-6140-3714 (unauthenticated)
Airat G. Kiiamov Kazan Federal University, 18 Kremlevskaja str., Kazan 420008, Russian Federation https://orcid.org/0000-0001-5376-7000 (unauthenticated)
Anna V. Astrakhantseva Kazan Federal University, 18 Kremlevskaja str., Kazan 420008, Russian Federation https://orcid.org/0000-0002-1670-3064 (unauthenticated)
Andrey A. Lyapin National Research Mordovia State University, 68 Bolshevitskaya str., Saransk 430005, Russia https://orcid.org/0000-0002-6963-9801 (unauthenticated)

DOI:

https://doi.org/10.17308/kcmf.2022.24/10256

Keywords:

Upconversion luminescence, External energy yield, Correlated color temperatures, Er3, Fluoride crystals, Solid solutions

Abstract

Increasing the efficiency of upconversion luminophores is an important problem in materials science. Here we report on approach of use of disordered crystals namely solid solutions BaY_1.8Lu_0.2F₈ doped with Er³⁺ ions to improve spectral characteristics and efficiency of upconversion from near IR spectral region. It is shown that investigated compound provide up to 9.4% of external energy yield of the up-conversion luminescence at an excitation power density of 6 W/cm2 at 1532 nm for the 10 at.% of Er³⁺ doping. Also the investigated crystals of BaY_1.8Lu_0.2F₈:Er³⁺ allow the control of the CCT parameter in the range of 2384–5149 K by changing the concentration and power density of the excitation. Advantages revealed in this work for crystalline compounds BaY_1.8Lu_0.2F₈:Er³⁺ such as wide absorption bands in the infrared spectral range, a high external energy yield, and a controllable distribution of intensity of luminescence bands makes them prospective to improve the efficiency of double-sided solar cells.

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Author Biographies

Alexey S. Nizamutdinov, Kazan Federal University, 18 Kremlevskaja str., Kazan 420008, Russian Federation

Cand. Sci. (Phys.–Math.),
Senior Researcher, Associate Professor, Kazan Federal
University (Kazan, Russian Federation).
Sergey V. Gushchin, National Research Mordovia State University, 68 Bolshevitskaya str., Saransk 430005, Russia

postgraduate student, National
Research Mordovia State University (Saransk, Russian
Federation).
Sergey A. Bukarev, National Research Mordovia State University, 68 Bolshevitskaya str., Saransk 430005, Russia

postgraduate student, National
Research Mordovia State University (Saransk, Russian
Federation).
Alexey A. Shavelev, Kazan Federal University, 18 Kremlevskaja str., Kazan 420008, Russian Federation

Junior Researcher, Kazan
Federal University (Kazan, Russian Federation).
Mikhail A. Marisov, Kazan Federal University, 18 Kremlevskaja str., Kazan 420008, Russian Federatio; Zavoisky Physical-Technical Institute, FRC Kazan Scientific Center of the Russian Academy of Sciences, 10/7 Sibirsky av., Kazan 420029, Russian Federation

Cand. Sci. (Phys.–Math.), Senior
Researcher, Kazan Physical-Technical Institute, Kazan
Federal University (Kazan, Russian Federation).
Ainur A. Shakirov, Kazan Federal University, 18 Kremlevskaja str., Kazan 420008, Russian Federation

Junior Researcher, Kazan Federal
University (Kazan, Russian Federation).
Airat G. Kiiamov, Kazan Federal University, 18 Kremlevskaja str., Kazan 420008, Russian Federation

Cand. Sci. (Phys.–Math.), Senior
Researcher, Kazan Federal University (Kazan, Russian
Federation).
Anna V. Astrakhantseva, Kazan Federal University, 18 Kremlevskaja str., Kazan 420008, Russian Federation

Laboratory Assistant,
Kazan Federal University (Kazan, Russian Federation)
Andrey A. Lyapin, National Research Mordovia State University, 68 Bolshevitskaya str., Saransk 430005, Russia

Cand. Sci. (Phys.–Math.),
Associate Professor, National Research Mordovia State
University (Saransk, Russian Federation).

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