Equilibrium in the System of Glauconite – Aqueous Solution of Cefepime Hydrochloride

  • Tatiana A. Krysanova Voronezh State University, 1, Universitetskaya pl., 394018 Voronezh, Russian Federation http://orcid.org/0000-0003-1720-6358
  • Diana L. Kotova Voronezh State University, 1, Universitetskaya pl., 394018 Voronezh, Russian Federation https://orcid.org/0000-0002-6060-088X
  • Mohammed T. Bestoon Voronezh State University, 1, Universitetskaya pl., 394018 Voronezh, Russian Federation
Keywords: sorption, glauconite, cefepime hydrochloride.

Abstract

The patterns of immobilization of cefepime hydrochloride on glauconite at a temperature of 295 K are established. The isotherm of sorption of cefepime hydrochloride from dilute solutions is described using the Langmuir theory. The values of the maximum capacity of the monolayer and the coefficient of the sorption equilibrium for cefepime hydrochloride are calculated. It is revealed that the monolayer binding of the antibiotic to glauconite is the result of an equivalent exchange with the extra-frame cations of the sorbent. The polymolecular nature of the sorption may be due to the formation of cefepime hydrochloride associates due to hydrogen bonds.

 

 

 

 

 

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Author Biographies

Tatiana A. Krysanova, Voronezh State University, 1, Universitetskaya pl., 394018 Voronezh, Russian Federation

Cand. Sci. (Chem.), Associate Professor, Department of Analytic Chemistry,
Voronezh State University, Voronezh, Russian Federation; e-mail: takrys@yandex.ru. 

Diana L. Kotova, Voronezh State University, 1, Universitetskaya pl., 394018 Voronezh, Russian Federation

Dr. Sci. (Chem.), Full Professor, Department of Analytical Chemistry, Voronezh
State University, Voronezh, Russian Federation

Mohammed T. Bestoon, Voronezh State University, 1, Universitetskaya pl., 394018 Voronezh, Russian Federation

undergraduate, Department of Analytical Chemistry, Voronezh State University,
Voronezh, Russian Federation

Published
2019-12-02
How to Cite
Krysanova, T. A., Kotova, D. L., & Bestoon, M. T. (2019). Equilibrium in the System of Glauconite – Aqueous Solution of Cefepime Hydrochloride. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 21(4), 528-533. https://doi.org/10.17308/kcmf.2019.21/2189
Section
Статьи