Influence of Bath Temperature on Structural, Optical and Electrical Properties of Cadmium Sulfi de Thin Films Prepared by Chemical Bath Deposition

  • Mikhail V. Gapanovich Institute of Problems of Chemical Physics of Russian Academy of Sciences, 1, Academician Semenov ave., 142432 Chernogolovka, Moscow Region, Russian Federation https://orcid.org/0000-0002-9109-6532
  • Natalia A. Tikhonina Institute of Problems of Chemical Physics of Russian Academy of Sciences, 1, Academician Semenov ave., 142432 Chernogolovka, Moscow Region, Russian Federation
  • Tatiana S. Kokovina Lomonosov Moscow State University, Faculty of Fundamental Physicochemical Engineering, 1, Leninskie Gory, GSP-1, 119991 Moscow Russian Federation
  • Dmitry N. Varseev Institute of Problems of Chemical Physics of Russian Academy of Sciences, 1, Academician Semenov ave., 142432 Chernogolovka, Moscow Region, Russian Federation. Lomonosov Moscow State University, Faculty of Fundamental Physicochemical Engineering, 1, Leninskie Gory, GSP-1, 119991 Moscow Russian Federation
  • Vladimir V. Rakitin Institute of Problems of Chemical Physics of Russian Academy of Sciences, 1, Academician Semenov ave., 142432 Chernogolovka, Moscow Region, Russian Federation https://orcid.org/0000-0001-6582-5212
  • Muniramaiah Reddivari S.V. University, Solar Photovoltaic Laboratory, Department of Physics Andhra Pradesh, 517502 Tirupati, India https://orcid.org/0000-0003-0903-3493
  • Babu Pejjai S.V. University, Solar Photovoltaic Laboratory, Department of Physics Andhra Pradesh, 517502 Tirupati, India https://orcid.org/0000-0001-5768-9433
  • Tulasi Ramakrishna Reddy Kotte S.V. University, Solar Photovoltaic Laboratory, Department of Physics Andhra Pradesh, 517502 Tirupati, India https://orcid.org/0000-0002-3457-6505
  • Gennady F. Novikov Institute of Problems of Chemical Physics of Russian Academy of Sciences, 1, Academician Semenov ave., 142432 Chernogolovka, Moscow Region, Russian Federation. Lomonosov Moscow State University, Faculty of Fundamental Physicochemical Engineering, 1, Leninskie Gory, GSP-1, 119991 Moscow Russian Federation https://orcid.org/0000-0002-5458-8263
Keywords: cadmium sulfi de,, CBD,, temperature effect,, structural change,, growth mechanism,, electrical properties

Abstract

Abstract. The effect of bath temperature (60-90 °C) on structural, optical and electrical properties
of CdS thin films deposited by chemical bath deposition (CBD) at a constant precursor
concentration and deposition time was studied. From the XRD analysis, it was found that the
structure of CdS thin fi lms varied with temperature. At lower temperature hexagonal structure
was dominated while at high temperature, the cubic structure was prominent. The band gap of
the as-prepared CdS thin fi lms was calculated from the UV-Vis spectroscopic data, and it was
found to be decreased with the increase of temperature. The resistivity of the CdS thin fi lms also
decreased with the increase in temperature.

 

 

 

REFERENCES
1. Kumar S., Sharma P., Sharma V. CdS nanofi lms: effect of deposition temperature on morphology and
optical band gap. Physica Scripta, 2013, v. 88(4), p. 045603. DOI:
https://doi.org/10.1088/0031-8949/88/04/045603
2. Rondiyaa S., Rokadea A., Gabhalea B., Pandharkara S., Chaudharia M., Dateb A., et al. Effect
of bath temperature on optical and morphology properties of CdS thin fi lms grown by chemical bath
deposition. Energy Procedia, 2017, v. 110, pp. 202–209. DOI: https://doi.org/10.1016/j.egypro.2017.03.128
3. Fangyang Liu, Yanqing Lai, Jun Liu, Bo Wang, Sanshuang Kuang, Zhian Zhang, et al. Characterization
of chemical bath deposited CdS thin fi lms at different deposition temperature. J. Alloys Compd., 2010,
v. 493(1–2), pp. 305–308. DOI: https://doi.org/10.1016/j.jallcom.2009.12.088
4. Hariech S., Aida M. S., Bougdira J., Belmahi M., Medjahdi G., Genиve D., et al. Cadmium sulfi de thin
fi lms growth by chemical bath deposition. J. Semicond., 2018, v. 39(3), p. 034004. DOI: https://doi.org/10.1088/1674-4926/39/3/034004
5. Mane R. S., Lokhande C. D. Chemical deposition method for metal chalcogenide thin fi lms. J. Mater.
Chem. Phys., 2000, v. 65(1), p. 1–31. DOI: https://doi.org/10.1016/s0254-0584(00)00217-0
6. Hodes G. Chemical solution deposition of semiconductor fi lms. Monograph, Boca Raton, CRC
Press, 2002, 388 p. DOI: https://doi.org/10.1201/9780203909096
7. George P. J., Sanchez-Juarez A., Nair P. K. Modifi cation of electrical, optical and crystalline propertiesof chemically deposited CdS fi lms by thermal diffusion of indium and tin. Semicond. Sci. Technol., 1996, v.
11(7), pp. 1090–1095. DOI: https://doi.org/10.1088/0268-1242/11/7/021
8. Oliva A. I., Solis-Canto O., Castro-Rodriguez R., Quintana P. Formation of the band gap energy on CdS
thin fi lms growth by two different techniques Thin Solid Films, 2001, v. 391(1), pp. 28–35. DOI: https://doi.org/10.1016/s0040-6090(01)00830-6
9. Lejmi N., Savadogo O. The effect of heteropolyacids and isopolyacids on the properties of
chemically bath deposited CdS thin fi lms. Sol. Energy Mater. Sol. Cells, 2001, v. 70(1), pp. 71–83. DOI: https://doi.org/10.1016/s0927-0248(00)00412-8
10. Gray D.E. American Institute of Physics Handbook. 3rd Edition, McGraw-Hill, New York, pp. 4–58.
11. Ravi Kant Choubey, Dipti Desai, Kale S. N., Sunil Kumar. Effect of annealing treatment and
deposition temperature on CdS thin fi lms for CIGS solar cells applications. J. Mater. Sci: Mater. in Elec.,
2016, v. 27(8), pp. 7890–7898. DOI: https://doi.org/10.1007/s10854-016-4780-2
12. Lo Y. S., Choubey R. K., Yu W. C., Hsu W. T., Lan C. W. Shallow bath chemical deposition of CdS
thin fi lm. Thin Solid Films, 2011, v. 520(1), pp. 217-223. DOI: https://doi.org/10.1016/j.tsf.2011.07.035
13. Cortes A., Gomez H., Marotti R. E., Riveros G., Dalchiele E. A. Grain size dependence of the bandgap
in chemical bath deposited CdS thin fi lms. Sol. Energy Mater. Sol. Cells, 2004, v. 82(1-2), pp. 21–34. DOI:
https://doi.org/10.1016/j.solmat.2004.01.002 
14. Ahmad F. R., Yakimov A., Davis R. J., Her J. H., Cournoyer J. R., Ayensu N. M. Effect of thermal annealing
on the properties of cadmium sulfi de deposited via chemical bath deposition. Thin Solid Films, 2013,
v. 535, pp. 166–170. DOI: https://doi.org/10.1016/j.tsf.2012.10.085
15. Rakhshani A. E., Al-Azab A. S. Characterization of CdS fi lms prepared by chemical-bath deposition.
J. Phys. Condens. Matter., 2000, v. 12, pp. 8745–8756. DOI: https://doi.org/10.1088/0953-8984/12/40/316
16. Al Kuhaimi S. A. // Vacuum, 1998, v. 51, pp. 349–55.
17. Zelaya-Angel O., Alvarado-Gil J. J., Lozada-Morales R., Vargas H., Ferreira da Silva A. Band-gap
shift in CdS semiconductor by photoacoustic spectroscopy: Evidence of a cubic to hexagonal lattice transition.
Appl. Phys. Lett., 1994, v. 64(3), pp. 291–293. DOI: https://doi.org/10.1063/1.111184
18. Chopra K. L. Thin Film Phenomena. McGraw-Hill, New York, 1969, 266 p.
19. Pattabi M., Uchil J. Synthesis of cadmium sulphide nanoparticles. Sol. Energy Mater. Sol. Cells, 2000,
v. 63(4), pp. 309–314. DOI: https://doi.org/10.1016/s0927-0248(00)00050-7
20. Hani Khallaf, Isaiah O. Oladeji, Guangyu Chai, Lee Chow. Characterization of CdS thin fi lms grown by
chemical bath deposition using four different cadmium sources. Thin Solid Films, 2008, v. 516(21), pp. 7306–
7312. DOI: https://doi.org/10.1016/j.tsf.2008.01.004
21. Sasikala G., Thilakan P., Subramanian C. Modifi cation in the chemical bath deposition apparatus,
growth and characterization of CdS semiconducting thin fi lms for photovoltaic applications. Sol. Ener gy
Mater. Sol. Cells, 2000, v. 62(3), pp. 275–293. DOI: https://doi.org/10.1016/s0927-0248(99)00170-1
22. Toma A., Vigil O., Alvarado-Gil J. J., Lozada-Morales R., Zelaya-Angel O., Vargas H., et al. Infl uence
of thermal annealings in different atmospheres on the band-gap shift and resistivity of CdS thin fi lms. J. Appl.
Phys., 1995, v. 78(4), p. 2204–2207. DOI: https://doi.org/10.1063/1.360136

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Author Biographies

Mikhail V. Gapanovich, Institute of Problems of Chemical Physics of Russian Academy of Sciences, 1, Academician Semenov ave., 142432 Chernogolovka, Moscow Region, Russian Federation

Cand. Sci. (Chem.), Senior Researcher, Institute of Problems of Chemical
Physics of Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation; e-mail:
gmw@icp.ac.ru.

Natalia A. Tikhonina, Institute of Problems of Chemical Physics of Russian Academy of Sciences, 1, Academician Semenov ave., 142432 Chernogolovka, Moscow Region, Russian Federation

Cand. Sci. (Chem.), Senior Engineer, Institute of Problems of Chemical Physics
of Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation; e-mail: evgenia-r@mail.ru.

Tatiana S. Kokovina, Lomonosov Moscow State University, Faculty of Fundamental Physicochemical Engineering, 1, Leninskie Gory, GSP-1, 119991 Moscow Russian Federation

student, Lomonosov Moscow State University, Faculty of Fundamental Physicochemical
Engineering, Moscow, Russian Federation.

Dmitry N. Varseev, Institute of Problems of Chemical Physics of Russian Academy of Sciences, 1, Academician Semenov ave., 142432 Chernogolovka, Moscow Region, Russian Federation. Lomonosov Moscow State University, Faculty of Fundamental Physicochemical Engineering, 1, Leninskie Gory, GSP-1, 119991 Moscow Russian Federation

student, Engineer, Institute of Problems of Chemical Physics of Russian Academy
of Sciences, Chernogolovka, Moscow Region; Lomonosov Moscow State University, Faculty of
Fundamental Physicochemical Engineering, Moscow, Russian Federation.

Vladimir V. Rakitin, Institute of Problems of Chemical Physics of Russian Academy of Sciences, 1, Academician Semenov ave., 142432 Chernogolovka, Moscow Region, Russian Federation

Vladimir V. Rakitin – Cand. Sci. (Chem.), Researcher, Institute of Problems of Chemical Physics
of Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation; e-mail: domityan@yandex.ru.

Muniramaiah Reddivari, S.V. University, Solar Photovoltaic Laboratory, Department of Physics Andhra Pradesh, 517502 Tirupati, India

Junior Research Fellow (Phys.), Solar Photovoltaic Laboratory, Department
of Physics, Sri Venkateswara University, Tirupati, Andhra Pradesh, India; e-mail: r.muniram1995@gmail.com.

Babu Pejjai, S.V. University, Solar Photovoltaic Laboratory, Department of Physics Andhra Pradesh, 517502 Tirupati, India

Ph.D, Associate Research, Solar Photovoltaic Laboratory, Department of Physics,
Sri Venkateswara University, Tirupati, Andhra Pradesh, India; e-mail: pdmj.babu@gmail.com.

Tulasi Ramakrishna Reddy Kotte, S.V. University, Solar Photovoltaic Laboratory, Department of Physics Andhra Pradesh, 517502 Tirupati, India

Ph.D (Phys.), Professor, Head of Solar Photovoltaic Laboratory, Department of Physics, Sri Venkateswara University, Tirupati, Andhra Pradesh, India; e-mail: ktrkreddy@gmail.com.

Gennady F. Novikov, Institute of Problems of Chemical Physics of Russian Academy of Sciences, 1, Academician Semenov ave., 142432 Chernogolovka, Moscow Region, Russian Federation. Lomonosov Moscow State University, Faculty of Fundamental Physicochemical Engineering, 1, Leninskie Gory, GSP-1, 119991 Moscow Russian Federation

Dr. Sci. (Phys.- Math.), Full Professor, Head of Laboratory, Institute of Problems
of Chemical Physics of Russian Academy of Sciences, Chernogolovka, Moscow Region; Lomonosov
Moscow State University, Faculty of Fundamental Physicochemical Engineering, Moscow, Russian
Federation; e-mail: gmw@icp.ac.ru.

Published
2019-12-19
How to Cite
Gapanovich, M. V., Tikhonina, N. A., Kokovina, T. S., Varseev, D. N., Rakitin, V. V., Reddivari, M., Pejjai, B., Reddy Kotte, T. R., & Novikov, G. F. (2019). Influence of Bath Temperature on Structural, Optical and Electrical Properties of Cadmium Sulfi de Thin Films Prepared by Chemical Bath Deposition. Condensed Matter and Interphases, 21(4), 490-497. https://doi.org/10.17308/kcmf.2019.21/2360
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