Synthesis, Microstructural and Electromagnetic Characteristics of Cobalt-Zinc Ferrite

Keywords: glycine-nitrate synthesis, cobalt-zinc ferrite, ferrimagnetic, microstructure, composite materials, magnetic permeability, dielectric permittivity.


In this study, cobalt-zinc ferrite (Co0.5Zn0.5Fe2O4) was obtained by the glycine-nitrate method followed by annealing in a high-temperature furnace at a temperature of 1300 °С. The qualitative composition and its microstructural characteristics were determined using energy-dispersive X-ray spectroscopy, X-ray diffraction analysis, and scanning electron microscopy.
The analysis of the micrographs demonstrated that the cobalt-zinc ferrite micropowder obtained after thermal annealing has an average particle size of 1.7±1 μm. The analysis of XRD data showed that the annealed cobalt-zinc ferrite micropowder has a cubic crystal structure with a lattice parameter of a = 8.415 Å. Using the Scherrer and Williamson-Hall equations we calculated the average sizes of the coherent scattering regions, which were commensurate with the size of crystallites: according to the Scherrer equation D = 28.26 nm and according to the Williamson-Hall equation D = 33.59 nm and the microstress value e = 5.62×10–4 in the ferrite structure.
Using a vector network analyser, the electromagnetic properties of a composite material based on synthesized cobalt-zinc ferrite were determined. The frequency dependences of the magnetic and dielectric permeability values from the measured S-parameters of the composite material (50% ferrite filler by weight and 50% paraffin) were determined using the Nicolson-Ross-Weir method and were in the range of 0.015–7 GHz. The analysis of the graphs of the dependence of the magnetic permeability on the frequency of electromagnetic radiation revealed a resonance frequency of fr ≈ 2.3 GHz. The discovered
magnetic resonance in the UHF range allows the obtained material to be considered as being promising for use as an effective absorber of electromagnetic radiation in the range of 2–2.5 GHz.





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Author Biographies

Alexander Ivanovich Goryachko, Kuban State University, 14, Stavropolskaya str., Krasnodar 350040, Russian Federation

PhD student,
Department of Theoretical Physics and Computer
Technologies, Faculty of Physics and Technology,
Kuban State University, Krasnodar, Russian Federation;

Sergey Nikolaevich Ivanin, Kuban State University, 14, Stavropolskaya str., Krasnodar 350040, Russian Federation

PhD student, Kuban
State University, Krasnodar, Russian Federation;

Vladimir Yurievich Buzko, Kuban State University, 14, Stavropolskaya str., Krasnodar 350040, Russian Federation

PhD in Chemistry,
Associate Professor, Department of Radiophysics and
Nanotechnology, Faculty of Physics and Technology,
Kuban State University, Krasnodar, Russian Federation;

How to Cite
Goryachko, A. I., Ivanin, S. N., & Buzko, V. Y. (2020). Synthesis, Microstructural and Electromagnetic Characteristics of Cobalt-Zinc Ferrite. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 22(4), 446-452.