Thermodynamic Properties of Terbium Tellurides

  • Samira Z. Imamaliyeva Institute of Catalysis and Inorganic Chemistry, Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku AZ-1143, Azerbaijan https://orcid.org/0000-0001-8193-2122
  • Dunya M. Babanly Institute of Catalysis and Inorganic Chemistry, Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku AZ-1143, Azerbaijan; Azerbaijan State Oil and Industry University, 6/21 Azadlıq ave., Baku AZ-1143, Azerbaijan https://orcid.org/0000-0002-8330-7854
  • Vladimir P. Zlomanov Lomonosov Moscow State University, GSP-1, Leninskie Gory, Moscow 119991, Russian Federation https://orcid.org/0000-0002-0327-4715
  • Mahammad B. Babanly Institute of Catalysis and Inorganic Chemistry, Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku AZ-1143, Azerbaijan; Baku State University, 23, Academic Zahid Khalilov str., Baku AZ-1073/1, Azerbaijan https://orcid.org/0000-0001-5962-3710
  • Dilgam B. Taghiyev Institute of Catalysis and Inorganic Chemistry, Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku AZ-1143, Azerbaijan https://orcid.org/0000-0001-6175-9035
Keywords: terbium tellurides, electromotive forces method, thermodynamic functions.

Abstract

The paper presents the results of a study of solid-phase equilibria in the Tb–Te system and the thermodynamic properties of terbium tellurides obtained by the methods of electromotive forces and X-ray diffraction analysis. Based on the experimental data, it was established that the TbTe, Tb2Te3, TbTe2 и TbTe3 compounds are formed in the system. For the investigations of the alloys from the two-phase regions TbTe3+Te, TbTe2+TbTe3, and Tb2Te3+TbTe2, the EMF of concentration cells relative to the TbTe electrode was measured. The EMF of concentration cells relative to the terbium electrode was measured for the TbTe+Tb2T3 region. The partial thermodynamic functions of TbTe and Tb in alloys were determined by
combining the EMF measurements of both types in the 300–450 K temperature range, based on which the standard thermodynamic functions of formation and standard entropies of the indicated terbium tellurides were calculated.

 

 

 

References
1. Jha A. R. Rare earth materials: properties and
applications. United States. CRC Press. 2014. 371 p.
DOI: https://doi.org/10.1201/b17045
2. Balaram V. Rare earth elements: A review of
applications, occurrence, exploration, analysis,
recycling, and environmental impact. Geoscience
Frontiers. 2019;10(4): 1285–1290. DOI: https://doi.org/10.1016/j.gsf.2018.12.005
3. Yarembash E. I., Eliseev A. A. Khal’kogenidy
redkozemel’nykh elementov [Chalcogenides of rare
earth elements). Moscow: Nauka Publ.; 1975. 258p.
(In Russ.)
4. Y-Sc., La-Lu. Gmelin Handbock of Inorganic
Chemistry. In: Hartmut Bergmann (Ed.), Rare Earth
Elements, 8th Edition, Springer-Verlag Heidelberg
GmbH. Berlin; 1987.
5. Muthuselvam I. P., Nehru R., Babu K. R.,
Saranya K., Kaul S. N., Chen S-M, Chen W-T, Liu Y.,
Guo G-Y, Xiu F., Sankar R. Gd2Te3 an antiferromagnetic
semimetal. J. Condens. Matter Phys. 2019;31(28):
285802-5. DOI: https://doi.org/10.1088/1361-648X/ab1570
6. Huang H., Zhu J.-J. The electrochemical
applications of rare earth-based nanomaterials.
Analyst. 2019;144(23): 6789–6811. DOI: https://doi.org/10.1039/C9AN01562K
7. Saint-Paul M., Monceau P. Survey of the
thermodynamic properties of the charge density wave
systems. Adv. Cond. Matter Phys. 2019: 1–5 DOI:
https://doi.org/10.1155/2019/2138264
8. Cheikh D., Hogan B. E., Vo T., Allmen P. V., Lee K.,
Smiadak D. M., Zevalkink A., Dunn B. S., Fleurial J-P.,
Bux S. L. Praseodymium telluride: A high temperature,
high- ZT thermoelectric material. Joule. 2018; 2(4):
698–709. DOI: https://doi.org/10.1016/j.joule.2018.01.013
9. Patil S. J., Lokhande A. C., Lee D. W, Kim J. H.,
Lokhande C. D. Chemical synthesis and supercapacitive
properties of lanthanum telluride thin film. Journal of
Colloid and Interface Science. 2017; 490: 147–153. DOI:
https://doi.org/10.1016/j.jcis.2016.11.020
10. Zhou X. Z., Zhng K. H. L, Xiog J., Park J-H,
Dickerson J-H., He W. Size- and dimentionality
dependent optical, mahnetic and magneto-optical
properties of binary europium-based nanocrystals:
EuX (X=O, S, Se, Te). Nanotechnology. 2016;27(19):
192001-5. DOI: https://doi.org/10.1088/0957-4484/27/19/192001
11. Okamoto H. Desk handbook phase diagram for
binary alloys. ASM International. 2000. 900 p.
12. Babanly M. B., Mashadiyeva L. F., Babanly D. M.,
Imamaliyeva S. Z., Tagiyev D. B., Yusibov Y. A.. Some
issues of complex studies of phase equilibria and
thermodynamic properties in ternary chalcogenide
systems involving Emf measurements. Russian Journal
of Inorganic Chemistry. 2019;64(13): 1649–1672. DOI:
https://doi.org/10.1134/s0036023619130035
13. Imamaliyeva S. Z., Babanly D. M., Tagiev D. B.,
Babanly M. B. Physicochemical aspects of development
of multicomponent chalcogenide phases having the
Tl5Te3 structure. A review. Russian Journal of Inorganic
Chemistry2018;63(13): 1703–1724 DOI: https://doi.org/10.1134/s0036023618130041
14. Massalski T. B. Binary alloys phase diagrams,
second edition. ASM International, Materials Park.
Ohio; 1990. 3835 p. DOI: https://doi.org/10.1002/adma.19910031215
15. Diagrammi sostoyaniya dvoynikh metallicheskikh
system [Diagrams of Binary Metallic Systems]
Handbook in 3 vols. Lyakishev N.P. (Ed.) Moscow:
Mashinostroenie Publ.; 1996, 1997, 2001. (In Russ.)
16. Eliseev A. A., Orlova I. G., Martynova L. F.,
Pechennikov A. V., Chechernikov V. I. Paramagnetism
of some terbium chalcogenides. Inorganic Materials.
1987;23: 1833–1835.
17. Mills K. C. Thermodynamic data for inorganic
sulphides, selenides, and tellurides. London:
Butterworth; 1974. 854 p.
18. Vassiliev V. P., Lysenko V. A. Gaune-Escard M.
Relationship of thermodynamic data with periodic law.
Pure and Applied Chemistry. 2019;91(6): 879–884. DOI:
https://doi.org/10.1515/pac-2018-0717
19. Vassiliev V. P., Lysenko V. A. New approach for
the study of thermodynamic properties of lanthanide
compounds. Electrochimica Acta. 2016;222: 1770–1775.
DOI: https://doi.org/10.1016/j.electacta.2016.11.075
20. Morachevsky A. G., Voronin G. F., Geyderich V. A.,
Kutsenok I. B. Elektrokhimicheskie metody issledovaniya
v t e r m o d i n a m i k e m e t a l l i c h e s k i k h s y s t e m .
[Electrochemical methods of investigation in
hermodynamics of metal systems]. Moscow:
Akademkniga Publ.; 2003. 334 p. Available at: https://elibrary.ru/item.asp?id=19603291 (In Russ.)
21. Babanly M. B., Yusibov Y. A. Elektrokhimicheskie
metody v termodinamike neorganicheskikh sistem
[Electrochemical methods in thermodynamics of
inorganic systems]. Baku: BSU Publ.; 2011. 306 p.
22. Imamaliyeva S. Z., Mehdiyeva I. F., Taghiyev D. B.
et al. Thermodynamic investigations of the erbium
tellurides by EMF method. Physics and Chemistry of
Solid State. 2020;21(2): 312–318. DOI: https://doi.org/10.15330/pcss.21.2.312-318
23. Hasanova G. S., Aghazade A. I., Yusibov Yu. A.,
Babanly M. B. Thermodynamic investigation of the
Bi2Se3-Bi2Te3 system by the EMF method. Kondensirovannye
sredy i mezhfaznye granitsy = Condensed
Matter and Interphases. 2020;22(3): 310–319. DOI:
https://doi.org/10.17308/kcmf.2020.22/2961
24. Imamaliyeva S. Z., Babanly D. M., Gasanly T. M.,
et al.: Thermodynamic properties of Tl9GdTe6 and
TlGdTe2. Russian Journal of Physical Chemistry A.
2018;92(11): 2111–2116. DOI: https://doi.org/10.1134/s0036024418110158
25. Mansimova S. H., Orujlu E. N., Sultanova S. G.,
Babanly M. B. Thermodynamic properties of Pb6Sb6Se17.
Kondensirovannye sredy i mezhfaznye granitsy =
Condensed Matter and Interphases. 2017;19(4): 536–
541. https://doi.org/10.17308/kcmf.2017.19/234
26. Imamaliyeva S. Z., Gasanly T. M., Mahmudova
M. A. Thermodynamic properties of GdTe compound.
Physics. 2017;22: 19–21. Available at: http://physics.gov.az/Dom/2017/AJP_Fizika_04_2017_en.pdf
27. Imamaliyeva S. Z., Musayeva S. S., Babanly D. M.,
Jafarov Y. I., Tagiyev D. B., Babanly M. B. Determination
of the thermodynamic functions of bismuth
chalcoiodides by EMF method with morpholinium
formate as electrolyte. Thermochim. Acta. 2019; 679:
178319–17825. DOI: https://doi.org/10.1016/j.tca.2019.178319
28. Baza dannykh termicheskikh konstant veshchestv.
Elektronnaya versiya pod. red. V. S. Yungmana. 2006
[Database of thermal constants of substances.
Electronic version V. S. Yungman (ed.). 2006]. Available
at: http://www.chem.msu.ru/cgi-bin/tkv.pl?show=welcome.html/welcome.html

Downloads

Download data is not yet available.

Author Biographies

Samira Z. Imamaliyeva, Institute of Catalysis and Inorganic Chemistry, Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku AZ-1143, Azerbaijan

PhD in Chemistry,
Assistance Professor, Institute of Catalysis and
Inorganic Chemistry, Azerbaijan National Academy of
Sciences, Baku, Azerbaijan; e-mail: samira9597a@gmail.com.

Dunya M. Babanly, Institute of Catalysis and Inorganic Chemistry, Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku AZ-1143, Azerbaijan; Azerbaijan State Oil and Industry University, 6/21 Azadlıq ave., Baku AZ-1143, Azerbaijan

DSc in Chemistry, Assistance
Professor, Institute of Catalysis and Inorganic
Chemistry, Azerbaijan National Academy of Sciences,
Azerbaijan State Oil and Industry University, Baku,
Azerbaijan; e-mail: dunya.babanly@ufaz.az.

Vladimir P. Zlomanov, Lomonosov Moscow State University, GSP-1, Leninskie Gory, Moscow 119991, Russian Federation

DSc in Chemistry, Professor,
Lomonosov Moscow State University, Moscow, Russian
Federation; e-mail: zlomanov1@mail.ru

Mahammad B. Babanly, Institute of Catalysis and Inorganic Chemistry, Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku AZ-1143, Azerbaijan; Baku State University, 23, Academic Zahid Khalilov str., Baku AZ-1073/1, Azerbaijan

DSc in Chemistry, Professor,
Corresponding Member of the Azerbaijan National
Academy of Sciences, Deputy-director of the Institute
of Catalysis and Inorganic Chemistry, Azerbaijan
National Academy of Sciences, Baku State University,
Baku, Azerbaijan; e-mail: babanlymb@gmail.com.

Dilgam B. Taghiyev, Institute of Catalysis and Inorganic Chemistry, Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku AZ-1143, Azerbaijan

Academician of the Azerbaijan
National Academy of Sciences, Director of the Institute
of Catalysis and Inorganic Chemistry, Azerbaijan
National Academy of Sciences, Baku, Azerbaijan;
e-mail: dtagiyev@rambler.ru

Published
2020-12-15
How to Cite
Imamaliyeva, S. Z., Babanly, D. M., Zlomanov, V. P., Babanly, M. B., & Taghiyev, D. B. (2020). Thermodynamic Properties of Terbium Tellurides. Condensed Matter and Interphases, 22(4), 453-459. https://doi.org/10.17308/kcmf.2020.22/3116
Section
Статьи