Nonlinear optical properties of single-walled carbon nanotubes/water dispersed media exposed to laser radiation with nano- and femtosecond pulse durations

  • Pavel N. Vasilevsky National Research University of Electronic Technology, 1 Shokina pl., Zelenograd, Moscow 124498, Russian Federation; Institute of Nanotechnology of Microelectronics of the Russian Academy of Sciences, 32a Leninsky pr., Moscow 119991, Russian Federation https://orcid.org/0000-0002-5733-8497
  • Mikhail S. Savelyev National Research University of Electronic Technology, 1 Shokina pl., Zelenograd, Moscow 124498, Russian Federation; Institute of Nanotechnology of Microelectronics of the Russian Academy of Sciences, 32a Leninsky pr., Moscow 119991, Russian Federation; I. M. Sechenov First Moscow State Medical University, 8-2 Trubetskaya ul., Moscow 119991, Russian Federation https://orcid.org/0000-0003-1255-0686
  • Sergey A. Tereshchenko National Research University of Electronic Technology, 1 Shokina pl., Zelenograd, Moscow 124498, Russian Federation; Institute of Nanotechnology of Microelectronics of the Russian Academy of Sciences, 32a Leninsky pr., Moscow 119991, Russian Federation https://orcid.org/0000-0002-3163-5741
  • Sergey V. Selishchev National Research University of Electronic Technology, 1 Shokina pl., Zelenograd, Moscow 124498, Russian Federation https://orcid.org/0000-0002-5589-7068
  • Alexander Yu. Gerasimenko National Research University of Electronic Technology, 1 Shokina pl., Zelenograd, Moscow 124498, Russian Federation; Institute of Nanotechnology of Microelectronics of the Russian Academy of Sciences, 32a Leninsky pr., Moscow 119991, Russian Federation; I. M. Sechenov First Moscow State Medical University, 8-2 Trubetskaya ul., Moscow 119991, Russian Federation https://orcid.org/0000-0001-6514-2411
Keywords: Laser radiation Limiters, Nano- and femtosecond radiation, Carbon nanotubes, Reverse saturable absorption, Spatial self-phase modulation, Z-scan, Radiation transfer equation

Abstract

The constant increase in the power of laser systems and the growth of potential fields for the application of lasers make the problem of protecting sensitive elements of electro-optical systems and visual organs from high-intensity radiation an urgent issue. Modern systems are capable of generating laser radiation in a wide range of wavelengths, durations, and pulse repetition rates. High-quality protection requires the use of a universal limiter capable of attenuating laser radiation, not causing colour distortion, and having a high transmission value when exposed to low-power radiation. For this, dispersed media based on carbon nanotubes with unique physicochemical properties can be used. Such media have constant values
of their absorption coefficient and refractive index when exposed to low-intensity laser radiation and change their properties only when the threshold value is reached.
The aim of this work was the study of the nonlinear optical properties of an aqueous dispersion of single-walled carbon nanotubes exposed to nano- and femtosecond radiation. For the characterization of the studied medium, Z-scan and fixed sample location experiments were used. The optical parameters were calculated using a threshold model based on the radiation transfer equation.
As a result of the experiments, it was shown that the aqueous dispersion of single-walled carbon nanotubes is capable of limiting radiation with wavelengths from the visible and near-IR ranges: nano- (532, 1064 nm) and femtosecond (810 nm). A description of nonlinear optical effects was proposed for when a medium is exposed to radiation with a nanosecond duration due to reverse saturable absorption and two-photon absorption. When the sample exposed for a femtosecond duration the main limiting effect is spatial self-phase modulation. The calculated optical parameters can be used to describe the behaviour of dispersions of carbon nanotubes when exposed to radiation with different intensities. The demonstrated effects allow us to conclude that it is promising to use the investigated media as limiters of high-intensity laser radiation
in optical systems to protect light-sensitive elements.

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Author Biographies

Pavel N. Vasilevsky, National Research University of Electronic Technology, 1 Shokina pl., Zelenograd, Moscow 124498, Russian Federation; Institute of Nanotechnology of Microelectronics of the Russian Academy of Sciences, 32a Leninsky pr., Moscow 119991, Russian Federation

Postgraduate Student, Engineer
in Institute of Biomedical Systems, National Research
University of Electronic Technology – MIET,
Zelenograd, Moscow, Russian Federation; Junior
Research Fellow, Institute of Nanotechnology of
Microelectronics of the Russian Academy of Sciences,
Moscow, Russian Federation; e-mail: pavelvasilevs@yandex.ru

Mikhail S. Savelyev, National Research University of Electronic Technology, 1 Shokina pl., Zelenograd, Moscow 124498, Russian Federation; Institute of Nanotechnology of Microelectronics of the Russian Academy of Sciences, 32a Leninsky pr., Moscow 119991, Russian Federation; I. M. Sechenov First Moscow State Medical University, 8-2 Trubetskaya ul., Moscow 119991, Russian Federation

PhD in Physics and Mathematics,
Assistant Professor in Institute of Biomedical Systems,
National Research University of Electronic
Technology – MIET, Zelenograd, Moscow, Russian
Federation; Research Fellow, Institute o f
Nanotechnology of Microelectronics of the Russian
Academy of Sciences, Moscow, Russian Federation;
Research Fellow, I. M. Sechenov First Moscow State
Medical University, Moscow, Russian Federation;
e-mail: savelyev@bms.zone

Sergey A. Tereshchenko, National Research University of Electronic Technology, 1 Shokina pl., Zelenograd, Moscow 124498, Russian Federation; Institute of Nanotechnology of Microelectronics of the Russian Academy of Sciences, 32a Leninsky pr., Moscow 119991, Russian Federation

DSc in Physics and
Mathematics, Professor in Institute of Biomedical
Systems, National Research University of Electronic
Technology – MIET, Zelenograd, Moscow, Russian
Federation; Research Fellow, Institute o f
Nanotechnology of Microelectronics of the Russian
Academy of Sciences, Moscow, Russian Federation;
e-mail: tsa@miee.ru

Sergey V. Selishchev, National Research University of Electronic Technology, 1 Shokina pl., Zelenograd, Moscow 124498, Russian Federation

DSc in Physics and
Mathematics, Director of Institute of Biomedical
Systems, National Research University of Electronic
Technology – MIET, Zelenograd, Moscow, Russian
Federation; e-mail: selishchev@bms.zone

Alexander Yu. Gerasimenko, National Research University of Electronic Technology, 1 Shokina pl., Zelenograd, Moscow 124498, Russian Federation; Institute of Nanotechnology of Microelectronics of the Russian Academy of Sciences, 32a Leninsky pr., Moscow 119991, Russian Federation; I. M. Sechenov First Moscow State Medical University, 8-2 Trubetskaya ul., Moscow 119991, Russian Federation

Dsc in Physics and
Mathematics, Assistant Professor in Institute of
Biomedical Systems, National Research University of
Electronic Technology – MIET, Zelenograd, Moscow,
Russian Federation; Research Fellow, Institute of
Nanotechnology of Microelectronics of the Russian
Academy of Sciences, Moscow, Russian Federation;
Head of the Laboratory of Biomedical Nanotechnology,
I. M. Sechenov First Moscow State Medical University,
Moscow, Russian Federation; e-mail: gerasimenko@bms.zone

References

Shin Y. C., Wu B., Lei S., Cheng G. J., Lawrence Yao Y. Overview of laser applications in manufacturing and materials processing in recent years. Journal of Manufacturing Science and Engineering. 2020;142(11): 110818. https://doi.org/10.1115/1.4048397

Kalisky Y. Y., Kalisky O. The status of high-power lasers and their applications in the battlefield. Optical Engineering. 2010;49(9): 091003. https://doi.org/10.1117/1.3484954

Nishizawa N. Ultrashort pulse fiber lasers and their applications. Japanese Journal of Applied Physics. 2014;53(9): 090101. http://dx.doi.org/10.7567/JJAP.53.090101

Kashaev N., Ventzke V., Çam G. Prospects of laser beam welding and friction stir welding processes for aluminum airframe structural applications. Journal of Manufacturing Processes. 2018;36: 571–600. https://doi.org/10.1016/j.jmapro.2018.10.005

Liaros N., Fourkas J. T. Ten years of two-color photolithography. Optical Materials Express. 2019;9(7): 3006–3020. https://doi.org/10.1364/OME.9.003006

Roberts H. W., Day A. C., O’Brart D. P. S. Femtosecond laser–assisted cataract surgery: a review. European Journal of Ophthalmology. 2020;30(3): 417–429. https://doi.org/10.1177/1120672119893291

Campbell P., Moore I. D., Pearson M. R. Laser spectroscopy for nuclear structure physics. Progress in Particle and Nuclear Physics. 2016;86: 127–180. https://doi.org/10.1016/j.ppnp.2015.09.003

Dekan M., František D., Andrej B., Jozef R., Dávid R., Josip M. Moving obstacles detection based on laser range finder measurements. International Journal of Advanced Robotic Systems. 2018;15(1): 1–18. https://doi.org/10.1177/1729881417748132

Bukin O. A., Babii M. Yu., Golik S. S., Il’in A. A., Kabanov A. M., Kolesnikov A. V., Kulchin Yu. N., Lisitsa V. V., Matvienko G. G., Oshlakov V. K., Shmirko K. A. Lidar sensing of the atmosphere with gigawatt laser pulses of femtosecond duration. Quantum Electronics. 2014;44(6): 563–569. https://doi.org/10.1070/QE2014v044n06ABEH015431

Goodin C., Carruth D., Doude M., Hudson C. Predicting the influence of rain on LIDAR in ADAS. Electronics. 2019;8(1): 89. https://doi.org/10.3390/electronics8010089

Farid N., Li C., Wang H., Ding H. Laser-induced breakdown spectroscopic characterization of tungsten plasma using the first, second, and third harmonics of an Nd: YAG laser. Journal of Nuclear Materials. 2013;433(1-3): 80–85. https://doi.org/10.1016/j.jnucmat.2012.09.002

Saylam K., Hupp J. R., Averett A. R., Gutelius W. F., Gelhar B. W. Airborne lidar bathymetry: assessing quality assurance and quality control methods with Leica Chiroptera examples. International Journal of Remote Sensing. 2018;39(8): 2518–2542. https://doi.org/10.1080/01431161.2018.1430916

Chomicki D., Kharchenko O., Skowronski L., Kowalonek J., Smokal V., Krupka O., Derkowska-Zielinska B. Influence of methyl group in a quinoline moiety on optical and light-induced properties of side-chain azo-polymers. Applied Nanoscience. 2021: 1–9. https://doi.org/10.1007/s13204-021-01764-0

Büyükekşi S. I., Karatay A., Orman E . B., Selçuki N. A., Özkaya A. R., Salih B., Elmali A., Şengül A. A novel AB 3-type trimeric zinc (ii)-phthalocyanine as an electrochromic and optical limiting material. Dalton Transactions. 2020;49(40): 14068–14080. https://doi.org/10.1039/D0DT02460K

Beverina . , Pagani G. A. , Sassi M. Multichromophoric electrochromic polymers: colour tuning of conjugated polymers through the side chain functionalization approach. Chemical Communications. 2014;50(41): 5413–5430. https://doi.org/10.1039/C4CC00163J

Savelyev M. S., Gerasimenko A. Y., Vasilevsky P. N., Fedorova Y. O., Groth T., Ten G. N., Telyshev D. V. Spectral analysis combined with nonlinear optical measurement of laser printed biopolymer composites comprising chitosan/SWCNT. Analytical biochemistry. 2020;598: 113710. https://doi.org/10.1016/j.ab.2020.113710

Eevon C., Halimah M. K., Zakaria A., Azurahanim C. A. C., Azlan M. N., Faznny M. F. Linear and nonlinear optical properties of Gd3+ doped zinc borotellurite glasses for all-optical switching applications. Results in Physics. 2016;6: 761–766. https://doi.org/10.1016/j.rinp.2016.10.010

Varma S. J., Kumar, J., Liu, Y., Layne, K., Wu, J., Liang, C., Nakanishi Y., Aliyan A. Yang W. Ajayan P. M., Thomas J. 2D TiS2 layers: a superior nonlinear optical limiting material. Advanced Optical Materials. 2017;5(24): 1700713. https://doi.org/10.1002/adom.201700713

Tutt L. W., Boggess T. F. A review of optical limiting mechanisms and devices using organics, fullerenes, semiconductors and other materials. Progress in Quantum Electronics.1993;17(4): 299–338. https://doi.org/10.1016/0079-6727(93)90004-S

Li R., Dong N., Ren F., Amekura H., Wang J., Chen F. Nonlinear absorption response correlated to embedded Ag nanoparticles in BGO single crystal: from two-photon to three-photon absorption. Scientific Reports. 2018;8(1): 1–8. https://doi.org/10.1038/s41598-018-20446-6

Miao R., Hu Y., Ouyang H., Tang Y., Zhang C., You J., Zheng X., Xu Z., Cheng X., Jiang T. A polarized nonlinear optical response in a topological insulator Bi2Se3–Au nanoantenna hybrid-structure for alloptical switching. Nanoscale. 2019;11(31): 14598–14606. https://doi.org/10.1039/C9NR02616A

Savelyev M. S., Vasilevsky P. N., Gerasimenko A. Y., Ichkitidze L. P., Podgaetsky V. M., Selishchev S. V. Nonlinear optical characteristics of albumin and collagen dispersions with single-walled carbon nanotubes. Materials Physics and Mechanics. 2018;37(2): 133–139. https://doi.org/10.18720/mpm.3722018_4

Savotchenko S. E. Periodic states near the plane defect with non-linear response separating non-linear self-focusing and linear crystals. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases. 2020;20(2): 255–262. https://doi.org/10.17308/kcmf.2018.20/517

Valligatla S., Haldar K. K., Patra A., Desai N. R. Nonlinear optical switching and optical limiting in colloidal CdSe quantum dots investigated by nanosecond Z-scan measurement. Optics & Laser Technology. 2016;84: 87–93. https://doi.org/10.1016/j.optlastec.2016.05.009

Zhang Y., Wang Y. Nonlinear optical properties of metal nanoparticles: a review. RSC Advances. 2017;7(71); 45129–45144. https://doi.org/10.1039/C7RA07551K

Kuzmina E. A., Dubinina T. V., Vasilevsky P. N., Saveliev M. S., Gerasimenko A. Y., Borisova N. E., Tomilova L. G. Novel octabromo-substituted lanthanide (III) phthalocyanines–Prospective compounds for nonlinear optics. Dyes and Pigments. 2021;185: 108871. https://doi.org/10.1016/j.dyepig.2020.108871

Papagiannouli I., Bourlinos A. B., Bakandritsos A., Couris S. Nonlinear optical properties of colloidal carbon nanoparticles: nanodiamonds and carbon dots. RSC Advances. 2014;4(76): 40152–40160. https://doi.org/10.1039/C4RA04714A

Gerasimenko A. Yu. Laser structuring of the carbon nanotubes ensemble intended to form biocompatible ordered composite materials. Kondensirovannye Sredy I Mezhfaznye Granitsy =Condensed Matter and Interphases. 2017;19(4): 489–501. https://doi.org/10.17308/kcmf.2017.19/227 (In Russ., absract in Eng.)

Atlukhanova L. B., Dolbin I. V., Kozlov G. V. The Physics of Interfacial Adhesion between a Polymer Matrix and Carbon Nanotubes (Nanofibers) in Nanocomposites. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases. 2020;22(2): 190–196. https://doi.org/10.17308/kcmf.2020.22/2822

Maurya S. K., Rout A., Ganeev R. A., Guo C. Effect of size on the saturable absorption and reverse saturable absorption in silver nanoparticle and ultrafast dynamics at 400 nm. Journal of Nanomaterials. 2019;2019: 1–13. https://doi.org/10.1155/2019/9686913

Tereshchenko S. A., Podgaetskii V. M., Gerasimenko A. Yu., Savel’ev M. S. Threshold effect under nonlinear limitation of the intensity of highpower light. Quantum Electronics. 2015;45(4): 315–320. https://doi.org/10.1070/QE2015v045n04ABEH015569

Tereshchenko S. A., Savelyev M. S., Podgaetsky V. M., Gerasimenko A. Yu., Selishchev S. V. Nonlinear threshold effect in the Z-scan method of characterizing limiters for high-intensity laser light. Journal of Applied Physics. 2 0 16; 120 (9): 093109. https://doi.org/10.1063/1.4962199

Savelyev M. S., Gerasimenko A. Y., Podgaetskii V. M., Tereshchenko S. A., Selishchev S. V., Tolbin A. Y. Conjugates of thermally stable phthalocyanine J-type dimers with single-walled carbon nanotubes for enhanced optical limiting applications. Optics & Laser Technology. 2019;117: 272–279. https://doi.org/10.1016/j.optlastec.2019.04.036

Tong Q., Wang Y. H., Yu X. X., Wang B., Liang Z., Tang M., Wu A. S., Zhang H. J., Liang F., Xie Y. F. Nonlinear optical and multi-photon absorption properties in graphene–ZnO nanocomposites. Nanotechnology. 2018;29(16): 165706. https://doi.org/10.1088/1361-6528/aaac13

Wang S., Dong Y., He C., Gao Y., Jia N., Chen Z., Song W. The role of sp 2/sp 3 hybrid carbon regulation in the nonlinear optical properties of graphene oxide materials. RSC Advances. 2017;7(84): 53643–53652. https://doi.org/10.1039/C7RA10505C

Li J., Zhang Z., Yi J., Miao L., Huang J., Zhang J., He Y., Huang B., Zhao C., Zou Y., Wen S. Broadband spatial self-phase modulation and ultrafast response of MXene Ti3C2Tx (T= O, OH or F). Nanophotonics. 2020;9(8): 2415–2424. https://doi.org/10.1515/nanoph-2019-0469

Stavrou M., Dalamaras I., Karampitsos N., Couris S. Determination of the nonlinear optical properties of ingle-and few-layered graphene dispersions under femtosecond laser excitation: electronic and thermal origin contributions. The Journal of Physical Chemistry C. 2020;124(49): 27241–27249. https://doi.org/10.1021/acs.jpcc.0c09959

Published
2021-11-24
How to Cite
Vasilevsky, P. N., Savelyev, M. S., Tereshchenko, S. A., Selishchev, S. V., & Gerasimenko, A. Y. (2021). Nonlinear optical properties of single-walled carbon nanotubes/water dispersed media exposed to laser radiation with nano- and femtosecond pulse durations. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 23(4), 496-506. https://doi.org/10.17308/kcmf.2021.23/3668
Section
Original articles