The quasi-binary Cu3In5S9 – FeIn2S4 section4

Shahri Seyfaly  Abdullaeva; Ikhtiyar Bahram oglu Bakhtiyarly; Ruksana Jalal Kurbanova; Ziyafat Mamed Mukhtarova

doi:10.17308/kcmf.2022.24/9257

Shahri Seyfaly Abdullaeva Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan https://orcid.org/0000-0003-1723-2783
Ikhtiyar Bahram oglu Bakhtiyarly Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan https://orcid.org/0000-0002-7765-0672
Ruksana Jalal Kurbanova Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan https://orcid.org/0000-0001-6467-0079
Ziyafat Mamed Mukhtarova Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan https://orcid.org/0000-0003-1222-969X

DOI: https://doi.org/10.17308/kcmf.2022.24/9257

Keywords: Microhardness, Phase diagram, System, section, Quasi-binary, Eutectic, Solid solution

Abstract

The Cu₃In₅S₉–FeIn₂S₄ section was studied by methods of physicochemical analysis; differential thermal (DTA), X-ray phase (XRD), microstructural (MSA) and microhardness measurement. Based on the results of the obtained data, a phase diagram of the Cu₃In₅S₉–FeIn₂S₄ section of the Cu₂S–In₂S₃–FeS ternary system was constructed. It was established that the Cu₃In₅S₉– FeIn₂S₄ section is a quasi-binary section of the ternary Cu₂S–In₂S₃–FeS systems and is eutectic by type with limited solubility based on both initial components. The liquidus of the system consists of two branches of primary crystallization of s1 (solid solution based on Cu₃In₅S₉) and s (solid solution based on FeIn₂S₄) phases. The eutectic point has coordinates: 1150 K
temperature and composition 42 mol% FeIn₂S₄. The boundaries of the solid solutions were also determined. The region of solid solutions based on Cu₃In₅S₉ extends to 3 mol. % FeIn₂S₄, the region of solid solutions based on FeIn₂S₄ extends to 5 mol. % Cu₃In₅S₉ at room temperature.

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Author Biographies

Shahri Seyfaly Abdullaeva, Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan

PhD student, Researcher

Ikhtiyar Bahram oglu Bakhtiyarly, Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan

Dr. Sci. in
Chemistry, Professor

Ruksana Jalal Kurbanova, Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan

PhD in Chemistry,
Associate Professor

Ziyafat Mamed Mukhtarova, Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan

PhD in Chemistry,
Associate Professor

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