The quasi-binary Cu3In5S9 – FeIn2S4 section4

  • Shahri Seyfaly Abdullaeva Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan https://orcid.org/0000-0003-1723-2783
  • Ikhtiyar Bahram oglu Bakhtiyarly Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan https://orcid.org/0000-0002-7765-0672
  • Ruksana Jalal Kurbanova Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan https://orcid.org/0000-0001-6467-0079
  • Ziyafat Mamed Mukhtarova Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan https://orcid.org/0000-0003-1222-969X
Keywords: Microhardness, Phase diagram, System, section, Quasi-binary, Eutectic, Solid solution

Abstract

The Cu3In5S9–FeIn2S4 section was studied by methods of physicochemical analysis; differential thermal (DTA), X-ray phase (XRD), microstructural (MSA) and microhardness measurement. Based on the results of the obtained data, a phase diagram of the Cu3In5S9–FeIn2S4 section of the Cu2S–In2S3–FeS ternary system was constructed. It was established that the Cu3In5S9– FeIn2S4 section is a quasi-binary section of the ternary Cu2S–In2S3–FeS systems and is eutectic by type with limited solubility based on both initial components. The liquidus of the system consists of two branches of primary crystallization of s1 (solid solution based on Cu3In5S9) and s (solid solution based on FeIn2S4) phases. The eutectic point has coordinates: 1150 K
temperature and composition 42 mol% FeIn2S4. The boundaries of the solid solutions were also determined. The region of solid solutions based on Cu3In5S9 extends to 3 mol. % FeIn2S4, the region of solid solutions based on FeIn2S4 extends to 5 mol. % Cu3In5S9 at room temperature.

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Author Biographies

Shahri Seyfaly Abdullaeva, Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan

PhD student, Researcher

Ikhtiyar Bahram oglu Bakhtiyarly, Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan

Dr. Sci. in
Chemistry, Professor

Ruksana Jalal Kurbanova, Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan

PhD in Chemistry,
Associate Professor

Ziyafat Mamed Mukhtarova, Institute of Catalysis and Inorganic Chemistry named after M. Nagiev of the Azerbaijan National Academy of Sciences, 113 H. Javid ave., Baku Az1143, Azerbaijan

PhD in Chemistry,
Associate Professor

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Published
2022-05-30
How to Cite
Abdullaeva, S. S., Bakhtiyarly, I. B. oglu, Kurbanova, R. J., & Mukhtarova, Z. M. (2022). The quasi-binary Cu3In5S9 – FeIn2S4 section4. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 24(2), 182-186. https://doi.org/10.17308/kcmf.2022.24/9257
Section
Original articles