Фазовые равновесия в четверной системе Cu-Sb-S-I в области составов CuI-SbSI-SbI3
Аннотация
Фазовые равновесия в четверной системе Cu–Sb–S–I исследованы в области составов CuI–SbSI–SbI3 методами дифференциального термического анализа и рентгенофазового анализа. Построены граничный квазибинарный разрез CuI–SbSI, два внутренних политермических разреза фазовой диаграммы, а также проекция поверхности ликвидуса. Определены области первичной кристаллизации фаз, типы и координаты нон- и моновариантных равновесий. В системе выявлены ограниченные твердые растворы на основе SbSI (b-фаза) и высокотемпературных модификаций CuI (α1- и α2-фазы). Образование α1 и α2 фаз сопровождается понижением температур полиморфных
переходов CuI и установлением метатектических (375 °С) и эвтектоидных (280 °С) реакций. Также было показано, что система характеризуется наличием широкой области несмешиваемости, которая покрывает значительную часть поверхности ликвидуса фаз CuI и SbSI
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