Развитие методов исследования и синтеза твердых фаз в научной школе Я. А. Угая. Обзор

  • Галина Владимировна Семенова Воронежский государственный университет, Университетская пл., 1, Воронеж 394018, Российская Федерация
  • Александр Юрьевич Завражнов Воронежский государственный университет, Университетская пл., 1, Воронеж 394018, Российская Федерация
Ключевые слова: фазовые равновесия, методы тензиметрии, соединения класса АIVВV, халькогениды индия и галлия, фазовые диаграммы

Аннотация

Более пятидесяти лет в Воронежском государственном университете существует научная школа, созданная Яковом Александровичем Угаем. Одним из направлений работ этой школы являлось создание физико-химические основ получения твердых фаз в системах с летучими компонентами, что предопределило необходимость развития методов исследования давления пара (тензиметрических методов). В статье делается акцент лишь на части работ сотрудников ВГУ, которые были посвящены исследованию и построению Р-Т-х диаграмм. В настоящем обзоре проводится анализ фазовых равновесий и природы промежуточных фаз в системах AIV – BV, AIV
– BV – СV и AIII – BVI. Вследствие особого характера катион-катионных и анион-анионных связей в этих соединениях существует заметная специфика свойств, что делает их перспективными, в частности, 2D материалами. Приводится обзор работ, посвященных построению Р-Т-х диаграмм и исследованию процессов дефектообразования в двойных и тройных системах на основе  соединений AIVBV. Необходимо подчеркнуть, что высокие значения давления пара требовали модернизации известных методик, что позволило проводить эксперименты при давлениях порядка 35-40 атмосфер. Изучение систем AIII - BVI осложняют, напротив, низкие величины давления паров над халькогенидами индия и галлия, а также сложный состав пара. Для такого рода систем был разработан метод вспомогательного компонента, возможности применения которого достаточно широки и не ограничиваются соединениями AIIIBVI. Создан и применен новый метод регулирования нестехиометрии с помощью селективных неразрушающих транспортных химических реакций (т. е. с участием вспомогательного компонента). Основа способа состоит во введении или удалении одного из компонентов образца при помощи селективной транспортной химической реакции. В заключении проведен анализ развития методов исследования и синтеза промежуточных фаз с варьируемым составом (свойствами) на примере рассмотренных систем

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Биографии авторов

Галина Владимировна Семенова, Воронежский государственный университет, Университетская пл., 1, Воронеж 394018, Российская Федерация

д. х. н., профессор, профессор кафедры общей и неорганической
химии, Воронежский государственный университет, Воронеж, Российская Федерация; e-mail:
semen157@chem.vsu.ru

Александр Юрьевич Завражнов, Воронежский государственный университет, Университетская пл., 1, Воронеж 394018, Российская Федерация

д. х. н., профессор, профессор кафедры общей и неорганической
химии, Воронежский государственный университет; Воронеж, Российская Федерация; e-mail:
Alzavr08@rambler.ru

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Опубликован
2021-08-17
Как цитировать
Семенова, Г. В., & Завражнов, А. Ю. (2021). Развитие методов исследования и синтеза твердых фаз в научной школе Я. А. Угая. Обзор. Конденсированные среды и межфазные границы, 23(3), 353-373. https://doi.org/10.17308/kcmf.2021.23/3526
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Обзор

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