Sorption capacity of ionotropic alginate hydrogels based on elemental analysis
Abstract
The article presents the results of a theoretical and experimental study of the sorption capacity of ionotropic hydrogels based on biopolymer polysaccharide chains of sodium alginate and cross-linked with divalent cations of various metals. The study of the microstructure and the elemental analysis of the hydrogels were performed by means of electron microscopy and energy dispersive microanalysis together with combinatorial methods. The study determined two types of sorption effects that can occur in sodium alginate hydrogels stabilized by alkaline earth methods. The capacity of chemical sorption of heavy metals bound with alginate chains by coordinate covalent bonds was determined experimentally and calculated using combinatorial methods. Based on the results of the elemental analysis of the hydrogels, we assessed the contribution of physical sorption of ion associates, which can be retained near alginate chains due to weaker bonds. An analysis of strontium alginate demonstrated that the introduction of carbon nanotubes in the structure of the hydrogel changes their sorption capacity and primarily increases the size of physically absorbed molecules
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