Polymer chromato-desorption systems for creating aqueous media with a specific analytical concentration
Abstract
In this paper, we study polymer chromato-desorption systems (CDS) designed to create aqueous media with a known analyte content. The relevance of the study is due to the need for new methods of standardization of analytical measurements, ensuring higher correctness, accuracy and precision of the measurements performed.
The developed CDS are composite materials based on epoxy resin containing an analyte - a synthetic dye - sorbed on nanodispersed silicon dioxide. The main objective of the work was to study the kinetics of analyte release into water under static conditions. For this purpose, an experiment was conducted that included daily replacement of the water in which the CDS samples were located, followed by analysis of the concentration of the desorbed analyte by HPLC.
The results showed that the analyte desorption process obeys a power dependence, which allows predicting the concentration of the analyte in the aqueous medium at different stages of the CDS operation. It was found that the key factors influencing the rate and extent of analyte release are its chemical structure, hydrophilicity, initial availability and interaction with the polymer matrix. The highest analyte release was observed for Quinoline Yellow and Ponceau 4R, the lowest desorption rate was characterized by less polar triphenylmethane dyes, which is explained by their molecular features. The developed CDSs are highly stable and can be used as standard samples for calibrating chromatographic equipment. Their use in analytical chemistry will improve the accuracy of quantitative determination of various compounds, especially in complex matrix environments. Prospects for further research are related to optimizing the composition of CDSs, as well as studying their behavior under dynamic conditions in both ideal and non-ideal aqueous environments.
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