Hyperbranched polymers as a modifiers of chromatographic (HPTLC) and electrophoretic (CE) systems
Keywords:
hyperbranched polymers, high-performance thin-layer chromatography, capillary electrophoresis, water soluble vitamins, amino acids.
Abstract
The experiments to identify the possibility of using functionalized by oligosaccharides
hyperbranched poly(ethyleneimine) as a component of chromatographic (HPTLC) and electrophoretic (CE)
systems on example of separation of hydrophilic analytes (water-soluble vitamins and amino acids) were
carried out. Modification procedures of stationary phase and working electrolyte were optimized. An increase
in efficiency (2-5 times) for riboflavin-5-phosphate of sodium, lysine, glutamic acid and tryptophan was
observed (HPTLC) and the fact of dynamic modification of wall quartz capillary was found.
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2. Jiang G., Chen W., Xia W. Chromophore-Containing Polymers for Trace Explosive
Sensors // Designed Monomers & Polymers. 2008. V.11. P.105.
3. Gopidas K.R., Leheny A.R., Caminetti G., Turro N.J., Tomalia D.A. Photophysical
Investigation of Similarities between Starburst Dendrimers and Anionic Micelles // J. Am.
Chem. Soc. 1991. V. 113. P. 7335.
4. Tanaka N., Tamagawa T., Hosoya K., Kimata K., Araki T., Terabe S. Starburst
Dendrimers as a Carriers in Electrokinetic Chromatography // Chem. Lett. 1992. V. 21. P.
959.
5. Chong-Qi Shou , Chang-Li Zhou, Chun-Bin Zhao , Zhi-Liang Zhang , Guan-Bin Li,
Li-Ren Chen. Preparation and evaluation of non-bonded hyperbranched polymer-coated
columns for capillary electrophoresis. Talanta 63 (2004) 887–891.
6. Pim G.H.M. Muijselaar, Henk A. Claessens, and Care1 A. Cramers, Johan F.G.A.
Jansen and E.W. Meijer, Ellen M.M. de Brabander-van den Berg and Sjoerd van der Wal.
Dendrimers as Pseudo-Stationary Phases in Electrokinetic Chromatography. J. High Resol.
Chromatogr. V. 18, 1995. P.121-123.
7. Kuzdzal S.A., Monnig C.A., Newkome G.R., Moorefield C.N. Dendrimer
Electrokinetic Capillary Chromatography: Unimolecular Micellar Behavior of Carboxylic
Acid Terminated Cascade Macromolecules// J. Chem. Soc. Chem.Commun. 1994. P. 2139.
8. Castagnola M., Cassiano L., Lupi A., Messana I., Patamia M., Rabino R., Rossetti D.,
Giardina B. Ion-exchange electrokinetic capillary chromatography with starburst (PAMAM)
dendrimers – a rout towards high-performance electrokinetic capillary
chromatography // J. Chromatogr. A. 1995. V. 694. P. 463.
9. Haynes J.L., Shamsi S.A., Dey J., Warner I.M. Use of a New Diaminobutane
Dendrimer in Electrokinetic Capillary Chromatography // J. Liq. Chrom. & Rel. Technol.
1998. V. 21. P. 611.
10. Ling F.H., Lu V., Svec F., Fréchet J.M.J. Effect of multivalency on the performance
of enantioselective separation media for chiral HPLC prepared by linking multiple
selectors to a porous polymer support via aliphatic dendrons. // J. Org. Chem. 2002. V. 67.
P. 1993.
11. Huang S.H., Li S.R., Bai Z.W., Pan Z. Q., Yin CQ. Synthesis of polymer-type chiral
stationary phases and their enantioseparation evaluation by high-performance liquid
chromatography // Chromatographia. 2006. V. 64. P. 641.
12. Sakai K., Teng T.C., Katada A., Harada T., Yoshida K., Yamanaka K., Asami
Y.,Sakata M., and Kunitake M. Designable Size Exclusion Chromatography Columns
Based on Dendritic Polymer-Modified Porous Silica Particles // Chem. Mater. 2003. V. 15. P. 4091.
Published
2019-11-21
How to Cite
Kartsova, L. A., & Dzema, D. V. (2019). Hyperbranched polymers as a modifiers of chromatographic (HPTLC) and electrophoretic (CE) systems. Sorbtsionnye I Khromatograficheskie Protsessy, 13(5). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/1679
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