Equilibrium of α-tocopherol and β-sitosterol adsorption onto MCM-41 and organic-inorganic composites
Keywords:
α-tocopherol, β-sitosterol, MCM-41, composite, adsorption equilibrium.
Abstract
The equilibrium of α-tocopherol and β-sitosterol adsorption from hexane solution onto parent
MCM-41 and aminosilane (MN) and chlorotrimethylsilane (MC1) composites has been studied. It is shown
that grafting allows to save high ordered structure with high specific area, large pore volume and narrow pore
size distribution of MCM-41. The distribution coefficients of these biological active substances between
solution and the sorbent phase are calculated. A significant influence of the interactions sorbate-sorbate,
sorbate-sorbent, sorbate-solvent interactions is established.
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References
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2. De Eduardo S. Boffetta P., Ronco A.L. [et al.] Plant Sterols and Risk of Stomach
Cancer: A Case-Control Study in Uruguay // Nutrition and Cancer. 2000. V.37. № 2. Р.140.
3. Ostlund R.E., Racette S.B., Stenson W.F. Inhibition of cholesterol absorption by
phytosterol-replete wheat germ compared with phytosterol-depleted wheat germ //
American Journal Clinical Nutrition. 2003. V.77. № 6. Р. 1385.
4. Экспериментальная витаминология (справочное руководство) / под ред.
Островского Ю. М. Мн.: Наука и техника, 1979. - 552 с.
5. Lechner M., Reiter B., Lorbeer E. Determination of tocopherols and sterols in
vegetable oils by solid-phase extraction and subsequent capillary gas chromatographic
analysis // J. Chromatogr. A. 1999. V.857. P. 231.
6. Czuppon T., Kemeny Z., Kovari E. [et al.] Process for recovery of plant sterols from
by-product of vegetable oil refining: pat. WO2004000979 Hungry // CEREOL
NÖVÉNYOLAJIPARI RT; appl. 02.07.2002; publ. 31.12.2003.
7. Sanchez-Perez A., Delgado-Zamarreno M.M., Bustamante-Rangel M. [et al.]
Automated analysis of vitamin E isomers in vegetable oils by continuous membrane
extraction and liquid chromatography - electrochemical detection // J. Chromatogr. A.
2000. V. 881. P. 229.
8. Ibanez E., Palacios J., Sefiorans F.J. [et al.] Determination of tocopherols by GC-MS
followed by SFE // Journal AOACS. 2000. V. 77. P. 187.
9. Huo J.Z. Determination of Vitamin E in Aquatic Organisms by High-Performance
Liquid Chromatography with Fluorescence Detection // Anal. Biochem. 1996. V. 242. P.
123.
10. Liu F., Wang J., Li L. [et al.] Adsorption of Direct Yellow 12 onto Ordered
Mesoporous Carbon and Activated Carbon // J. Chem. Eng. Data. 2009. V. 54. P. 3043.
11. Vinu A., Hossain K.Z., Satish Kumar G. [et al.] Adsorption of amino acid on
mesoporous molecular sieves // Stud. Surf. Sci. Catal. 2005. V. 156. P. 631.
12. Miyahara M., Vinu A., Ariga K. Adsorption myoglobin over mesoporous silica
molecular sieves: Pore size effect and pore-filling model // Materials Science and
Engineering C. 2007. V. 27. № 2. P. 232.
13. Chandrasekar G., Vinu A., Murugesan V. [et al.] Adsorption of vitamin E on
mesoporous silica molecular sieves // Stud. Surf. Sci. Catal. 2005. V. 158. P. 1169.
14. Vinu A., Miyahara M., Hossain K.Z. [et al.] Adsorption of lysozyme over
mesoporous carbons with various pore diameters // Stud. Surf. Sci. Catal. 2005. V. 156. P.
637.
15. Hartmann M., Vinu A., Chandrasekar G. Adsorption of Vitamin E on Mesoporous
Carbon Molecular Sieves // Chem. Mater. 2005. V. 17. № 4. P. 829.
16. Beck J.S., Vartuli J.C., Roth W.J. [et al.] A new family of mesoporous molecular
sieves prepared with liquid crystal templates // J. Am. Chem. Soc. 1992. V. 114. P. 10834.
17. Kresge C.T., Leonowicz M.E., Roth W.J. [et al.] Ordered mesoporous molecular
sieves synthesized by a liquid-crystal template mechanism // Nature. 1992. V.359. P. 710.
18. Hoffmann F., Cornelius M., Morell J. [et al.] Silica-Based Mesoporous Organic–
Inorganic Hybrid Materials // Angew. Chem. Int. Ed. 2006. V. 45. P. 3216.
19. Kailasam K., Müller K. Physico-chemical characterization of MCM-41 silica
spheres made by the pseudomorphic route and grafted with octadecyl chains // J.
Chromatogr. A. 2008. Vol.1191. P. 125.
20. Gimeno E., Calero E., Castellote A.I. [et al.] Simultaneous determination of α-
tocopherol and β-carotene in olive oil by reserved-phase high performance
chromatography // J. Chromatogr. A. 2000. V. 881. P. 255.
21. Giacometti J. Determination of aliphatic alcohols, squalene, -tocopherol and
sterols in olive oils: direct method involving gas chromatography of the unsaponifiable
fraction following silylation // Analyst. 2001. V. 126. P. 472.
22. Brunauer S., Emmett P.H., Teller E. Adsorption of Gases in Multimolecular Layers
// J. Am. Chem. Soc. 1938. V. 60. P. 309.
23. Barrett E.P., Joyner L.G., Halenda P.P.J. The Determination of Pore Volume and
Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms // J.
Am. Chem. Soc. 1951. V. 73. P. 373.
24. Sing K.S.V. Everett D.H., Haul R.A.W. [et al.] Reporting physisorption data for
gas/solid systems // Pure & Appl. Chem. 1985. V. 57. № 4. P. 603.
25. Хохлова О.Н., Еременко В.А. Влияние температуры на необменную сорбцию
ароматических аминокислот низкоосновным анионообменником АН-31 //
Сорбционные и хроматографические процессы. 2007. Т. 7, вып. 6. С. 1032.
26. Kovalenko G.A., Kuznetsova E.V. Adsorption of antiseptics (furacilin,
chlorhexidine) and vitamin E on carbon-containing enterosorbents // Pharmaceutical
Chemistry Journal. 2000. V. 34. № 6. P. 327.
27. Langmuir J. The Constitution and fundamental properties of solids and liquids. I.
Solids // J. Am. Chem. Soc. 1916. V. 38. № 11. P.2221
Published
2019-11-25
How to Cite
Krizhanovskaya, O. O., Karpov, S. I., Borodina, E. V., Selemenev, V. F., Frank, R., Korabelnikova, E. O., & Belanova, N. A. (2019). Equilibrium of α-tocopherol and β-sitosterol adsorption onto MCM-41 and organic-inorganic composites. Sorbtsionnye I Khromatograficheskie Protsessy, 12(4). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/1841
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