Physical and chemical properties of acid activated clinoptilolite tuff

  • Thi Long Do The postgraduate student of chemical faculty, The Voronezh State University, Voronezh, e-mail: longdt83@mail.ru
  • Diana L. Kotova Dr. Sci. (Chemistry), professor, of Department of analytical chemistry, The Voronezh State University, Voronezh
  • Tatyana A. Krisanova Cand. Sci., (Chemistry), associate professor, Department of Analytic Chemistry, Voronezh State University, email: kris_SL_TN@mail.ru
  • Marina S. Bolotova the student of chemical faculty, The Voronezh State University, Voronezh
  • Yuri V. Sokolov Cand. Sci., (Physical) PhD, associate professor of Physics of Semiconductors and Microelectronics
  • Boris N. Beketov Dr.Sci (Pharmacy). professor, Tyumen State Medical Academy
  • Emma A. Dolgopolova senior researcher Center of Collective Use of Scientific Equipment, The Voronezh State University, Voronezh
Keywords: clinoptilolite tuff, acid activation, dealumination.

Abstract

The paper presents results of investigation of physicochemical characteristics of clinoptilolite
tuff before and after treated by hydrochloric acid. Nature of the change in the composition, structure and
properties of the sorbent in the process activation was analyzed. It was noted the change in the order of
extraction of cations with increasing acid concentration. Established that treatment with hydrochloric acid
concentration of ≥ 4,0 M accompanied by a significant increase in the ratio of Si/Al. During acid
activation, occurs the redistribution of water in the structure of the sorbent and its increase in sorption
capacity. It was shown that the extraction of aluminum 5,0 M acid leads to partial amorphization of the
zeolite phase and the insignificant change in crystallinity

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Published
2019-11-26
How to Cite
Do, T. L., Kotova, D. L., Krisanova, T. A., Bolotova, M. S., Sokolov, Y. V., Beketov, B. N., & Dolgopolova, E. A. (2019). Physical and chemical properties of acid activated clinoptilolite tuff. Sorbtsionnye I Khromatograficheskie Protsessy, 11(1). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/1905