Physical and chemical properties of acid activated clinoptilolite tuff
Abstract
The paper presents results of investigation of physicochemical characteristics of clinoptilolite
tuff before and after treated by hydrochloric acid. Nature of the change in the composition, structure and
properties of the sorbent in the process activation was analyzed. It was noted the change in the order of
extraction of cations with increasing acid concentration. Established that treatment with hydrochloric acid
concentration of ≥ 4,0 M accompanied by a significant increase in the ratio of Si/Al. During acid
activation, occurs the redistribution of water in the structure of the sorbent and its increase in sorption
capacity. It was shown that the extraction of aluminum 5,0 M acid leads to partial amorphization of the
zeolite phase and the insignificant change in crystallinity
Downloads
References
2.Клиноптилолит – труды симпозиума по вопросам исследования и применения
клиноптилолита / Тбилиси, 2-4 ноября 1974 / под. ред. Г.В. Цивишвили, Т.Г.
Андроникашвили, А.Ю. Крупенникова / Изд-во “Мецниереба”, 1977. 244 с.
3.Beyer H.K. Dealumination Techniques for Zeolites // Molecular Sieves - Science and
Technology. 2002. V. 3. P. 203-255.
4.Krohn J.E., Tsapatsis M. / Amino acid adsorption on Zeolit β // Langmuir. 2005. V.21.
P. 8743-8750.
5.Черенкова Ю.А. и др. Сорбционные и физико-химические свойства цеолита
приполярного Урала Югры // Сорбц. и хроматограф. процессы. 2006. Т.6. вып. 6. Ч.4.
С.1455 – 1459.
6.Казицына Л.А. Куплетская Н.Б. Применение УФ-, ИК- и ЯМР-спектроскопии в
органической химии. М. : Высш. школа, 1971. 264 с.
7.Наканиси К. Инфракрасная спектроскопия и строение органических соединений.
Москва: Мир, 1987. 188 с.
8.Акимова М.К. Влияние кислотной и щелочной активации на сорбционно-
структурные свойства глин: дис. канд. хим. наук: 020001: защищена 22.04. 1973:
утверждена 01.08.1973. М.,1973. 340 с.
9.Rozic M. et al. Decationization and dealumination of clinoptilolite tuff and ammonium
exchange on acid-modified tuff // Journal of Colloid and Interface Science. 2005. V.284. P.
48-56.
10. Garcia-Basabe Y. et al. Step-wise dealumination of natural clinoptilolite: Structural
and physicochemical characterization // Microporous and Mesoporous Materials. 2010.
V.135. P. 187-196.
11. Rodriguez-Fuentes G. et al. Solid state multinuclear NMR study of iron species in
natural and modified clinoptilolite from Tasajera deposit (Cuba) // Microporous and
Mesoporous Materials. 2008. V. 111. P.577-590.
12. Комаров В.С. и др. Исследование физико-химических свойств и механизма
образования фероцианид-алюмосиликатных сорбентов // Журнал неорганической
химии. 1994. Т.39. № 3. С. 378–380.
13. Roberge D. M. et al. Dealumination of zeolite beta by acid leaching: a new insight
with two-dimensional multi-quantum and cross polarization 27Al MAS NMR // Phys.
Chem. Chem. Phys. 2002. V.4. P.3128-3135