Unsymmetrical diaryltelluroxides investigation by RP HPLC-MS method
Keywords:
diaryltelluroxides mixture analysis, reserved phase high performance liquid chromatography with mass spectrometry detection, electrospray and APCI ionization.
Abstract
The diaryltelluroxides with various substitutions in benzene rings, “unsymmetrical”, yielded by
heating of the corresponding symmetrical substances, was investigated by RP HPLC-MS method. It was
found, that chromatographic retention of the corresponding “unsymmetrical” substances had intermediate
value between retention of the symmetrical analogs. A research ability of similar unresolved mixtures by
characteristic ions was shown. Mass spectral data interpretation of the investigated compounds forming in
mass spectra of the overlapped chromatographic peaks was studied. The isomeric dimmers, allowing to
reliably identify presence of “unsymmetrical” compounds was found
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References
1. Редькин Н.А., Гарькин В.П., Ульянов А.В., Буряк А.К. Газовая хроматография –
масс-спектрометрия в исследовании теллурорганических соединений //
Сорбционные и хроматографические процессы. 2007. Т.7, №1. С. 37-43.
2. Садеков И.Д., Минкин В.И. Специфика реакционной способности
теллурорганических соединений. // Успехи химии. 1995. Т 64. С. 527–561.
3. You Y., Ahsan K., Detty M.R. Mechanistic Studies of the Tellurium(II)/Tellurium(IV)
Redox Cycle in Thiol Peroxidase-like Reactions of Diorganotellurides in Methanol //
Journal of American Chemical Society. 2003.
V. 125. P. 4918-4927.
4. Robert E. Ardrey, Liquid Chromatography - Mass Spectrometry: An Introdaction //
Wiley, Chichester, 2003. 288 p.
5. Wilfried M.A. Niessen, Liquid Chromatography Mass Spectrometry Niessen // CRC
Press. Boca Raton. 2006. 602 p.
6. Simon J.Gaskell «Electrosprey. Principles and Practice» // J. Mass Spectrom., 1997.
V. 32. P. 677-688.
7. Шатц. В.Д., Сахартова О.В. Высокоэффективная жидкостная хроматография.
Рига: Зинатне. 1988. 390 с.
масс-спектрометрия в исследовании теллурорганических соединений //
Сорбционные и хроматографические процессы. 2007. Т.7, №1. С. 37-43.
2. Садеков И.Д., Минкин В.И. Специфика реакционной способности
теллурорганических соединений. // Успехи химии. 1995. Т 64. С. 527–561.
3. You Y., Ahsan K., Detty M.R. Mechanistic Studies of the Tellurium(II)/Tellurium(IV)
Redox Cycle in Thiol Peroxidase-like Reactions of Diorganotellurides in Methanol //
Journal of American Chemical Society. 2003.
V. 125. P. 4918-4927.
4. Robert E. Ardrey, Liquid Chromatography - Mass Spectrometry: An Introdaction //
Wiley, Chichester, 2003. 288 p.
5. Wilfried M.A. Niessen, Liquid Chromatography Mass Spectrometry Niessen // CRC
Press. Boca Raton. 2006. 602 p.
6. Simon J.Gaskell «Electrosprey. Principles and Practice» // J. Mass Spectrom., 1997.
V. 32. P. 677-688.
7. Шатц. В.Д., Сахартова О.В. Высокоэффективная жидкостная хроматография.
Рига: Зинатне. 1988. 390 с.
Published
2019-11-27
How to Cite
Rodina, T. A., Gar`kinV. P., Red`kinN. A., & Buryak, A. K. (2019). Unsymmetrical diaryltelluroxides investigation by RP HPLC-MS method. Sorbtsionnye I Khromatograficheskie Protsessy, 10(2). Retrieved from https://journals.vsu.ru/sorpchrom/article/view/2035
Section
Статьи
