Activity and stability of PtCo/C electrocatalysts for alcohol oxidation
Abstract
This study considers the liquid-phase synthesis of PtCo/C catalysts based on CoOx/C composite carriers with different mass fractions of metals and Pt:Co ratios. The purpose of the article is to study the activity of PtCo/C electrocatalysts of various compositions in the oxidation reactions of methanol and ethanol and to compare their characteristics with their commercial PtRu/C and Pt/C analogues.
PtCo/С catalysts were synthesised with Pt:Co ratios of 1:1 and 3:1. The specific active surface of the obtained PtCo/C materials was determined, their activity in the oxidation reactions of methanol and ethanol and their resistance to poisoning by intermediate products of alcohol oxidation were studied. The structural and electrochemical characteristics of the obtained PtCo/C catalysts were studied by X-ray diffraction, cyclic voltammetry, and chronoamperometry. It was found that PtCo/C materials with a mass fraction of platinum close to 20% are the most active and stable as compared to their commercial PtRu/C and Pt/C analogues.
The presented results show that PtCo/C catalysts are a promising material for direct alcohol fuel cells.
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Sundarrajan S., Allakhverdiev S. I., Ramakrishna. S. Progressand perspectives in micro direct methanol fuel cell. Int J of Hydrogen Energy. 2012;37(10): 8765–8786. https://doi.org/10.1016/j.ijhydene.2011.12.017
Yaroslavtsev A. B., Dobrovolsckiy Yu. A., Shaglaeve N. S., Frolova L. A., Gerasimova E. V., Sanginov E. A. Nanostructured materials developed for the low temperature fuel elements, Russian Chemical Reviews. 2012;81(3) 191–201. https://doi.org/10.1070/RC2012v081n03ABEH004290
Karim N. A., Kamarudin S. K. Introduction to direct alcohol fuel cells (DAFCs). Direct Liquid Fuel Cells. 2021: 49–70. https://doi.org/10.1016/B978-0-12-818624-4.00002-9
Wang X. X., Swihart M. T., Wu G. Achievements, challenges andperspectives on cathode catalysts in proton exchangemembrane fuel cells for transportation. Nature Catalysis. 2019;2: 578–589. https://doi.org/10.1038/s41929-019-0304-9
Menshikov V. S., Novomlinsky I. N., Belenov S. V., Alekseenko A. A., Safronenko O. I., Guterman V. E. Methanol, ethanol, and formic acid oxidation on new platinum-containing catalysts. Catalysts. 2021;11: 1–18. https://doi.org/10.3390/catal11020158
Petrii O. A. The progress in understanding the mechanisms of methanol and for micacid electrooxidation on platinum group metals. Russian Journal of Electrochemistry. 2019;55: 1-33. https://doi.org/10.1134/S1023193519010129
Vigier F., Coutanceau C., Hahn F., Belgsir E. M., Lamy, C. On the mechanism of ethanol electro-oxidation on Pt and PtSn catalysts: electrochemical and in situ IR reflectance spectroscopy studies. Journal of Electroanalytical Chemistry. 2004;563(1): 81–89. https://doi.org/10.1016/j.jelechem.2003.08.019
Chen A., Holt-Hindle P. Platinum-based nanostructuredmaterials properties, and applications. Chemical Reviews. 2010;110(6): 3767–3804. https://doi.org/10.1021/cr9003902
Shi G. Y., Yano H., Tryk D. A., Watanabe M., Uchida H. A novel Pt–Co alloy hydrogen anode catalyst with superlative activity, CO-tolerance and robustness. Nanoscale. 2016;8: 13893–13897. https://doi.org/10.1039/c6nr00778c
Antolini E., Salgado J. R. C., Gonzalez E. R. The methanol oxidation reaction on platinum alloys with the first row transition metals: The case of Pt-Co and -Ni alloy electrocatalysts for DMFCs: A short review. Applied Catalysis B: Environmental. 2006;63(1–2): 137–149. https://doi.org/10.1016/j.apcatb.2005.09.014
Baronia R., Goel J., Tiwari S., Singh P. Efficient electro-oxidation of methanol using PtCo nanocatalysts supported reduced graphene oxide matrix as anode for DMFC. International Journal of Hydrogen Energy. 2017;42(15): 10238–10247. https://doi.org/10.1016/j.ijhydene.2017.03.011
Xu Y., Yuan Y., Ma A., Wu X., Liu Y., Zhang B. Composition-tunable Pt-Co alloy nanoparticle networks: facile room-temperature synthesis and supportless electrocatalytic applications. ChemPhysChem. 2012;13: 2601–2609. https://doi.org/10.1002/cphc.201100989
Sorsa O., Romar H., Lassi U., Kallio T. Co-electrodeposited mesoporous PtM (M=Co, Ni, Cu) as an active catalyst for oxygen reduction reaction in a polymer electrolyte membrane fuel cell. Electrochimica Acta. 2017;230: 49–57. https://doi.org/10.1016/j.electacta.2017.01.158
Mohl M., Dobo D., Kukovecz A., … Ajayan P. M. Formation of CuPd and CuPt bimetallic nanotubes by galvanic replacement reaction. The Journal of Physical Chemistry C. 2011;115: 9403–9409. https://doi.org/10.1021/jp112128g
Wang X, Zhang L., Wang F., Yu J., Zhu H. Nickel-introduced structurally ordered PtCuNi/C as high performance electrocatalyst for oxygen reduction reaction. Progress in Natural Science: Materials Inter-national. 2020;30(6): 05–911. https://doi.org/10.1016/j.pnsc.2020.10.017
Asset T., Chattot R., Fontana M., … Maillard F. A Review on recent developments and prospects for the oxygen reduction reaction on hollow Pt-alloy nanoparticles. ChemPhysChem. 2018;19: 1552–1567. https://doi.org/10.1002/cphc.201800153
Jalan V. M., Taylor E. J. Importance of interatomic spacing in catalytic reduction of oxygen in phosphoric acid. Journal of The Electrochemical Society. 1983; 130(11): 2299–2302. https://doi.org/10.1149/1.2119574
Toda T., Igarashi H., Uchida H., Watanabe M. Enhancement of the electroreduction of oxygen on Pt Alloys with Fe, Ni, and Co. Journal of The Electrochemical Society. 1999;146: 3750–3756. https://doi.org/10.1149/1.1392544
Munoz M., Ponce S., Zhang G. R., Etzold B. J. M. Size-controlled PtNi nanoparticles as highly efficient catalyst for hydrodechlorination reactions. Applied Catalysis B: Environmental. 2016;192: 1–7. https://doi.org/10.1016/J.APCATB.2016.03.038
Konno N., Mizuno S., Nakaji H., Ishikawa Y. Development of compact and high- performance fuel cell stack. SAE International Journal of Alternative Powertrains. 2015;4(1): 123–129. https://doi.org/10.4271/2015-01-1175
Ding J., Ji S., Wang H., Pollet B. G., Wang R. Tailoring nanopores within nanoparticles of PtCo networks as catalysts for methanol oxidation reaction. Electrochimica Acta. 2017;255: 55–62. https://doi.org/10.1016/j.electacta.2017.09.159
Li Z., Jiang X., Wang X., … Tang Y. Concave PtCo nanocrosses for methanol oxidation reaction. Applied Catalysis B: Environmental. 2020;270: 119135–119160. https://doi.org/10.1016/j.apcatb.2020.119135
Xu C., Hou J., Pang X., Li X., Zhu M., Tang B. Nanoporous PtCo and PtNi alloy ribbons for methanol electrooxidation. International Journal of Hydrogen Energy. 37(14), 10489–10498. https://doi.org/10.1016/j.ijhydene.2012.04.041
Flórez-Montaño J., García G., Guillén-Villafuerte O., Rodríguez J. L., Planes G. A., Pastor E. Mechanism of ethanol electrooxidation on mesoporous Pt electrode in acidic medium studied by a novel electrochemical mass spectrometry set-up. Electrochimica Acta. 2016;209: 121–131. https://doi.org/10.1016/j.electacta.2016.05.070
Bonesi A., Garaventa G., Triaca W., Castro Luna A. Synthesis and characterization of new electrocatalysts for ethanol oxidation. International Journal of Hydrogen Energy. 2008;33(13): 3499–3501. https://doi.org/10.1016/j.ijhydene.2007.12.056
Parreira L. S., Antoniassi R. M., Freitas I. C., de Oliveira D. C., Spinacé E. V., Camargo P. H. C., dos Santos M. C. MWCNT-COOH supported PtSnNi electrocatalysts for direct ethanol fuel cells: Low Pt content, selectivity and chemical stability. Renewable Energy. 2019;143: 1397–1405. https://doi.org/10.1016/j.renene.2019.05.067
Li J., Jilani S. Z., Lin H., … Sun S. Ternary CoPtAu nanoparticles as a general catalyst for highly efficient electro-oxidation of liquid fuels. Angewandte Chemie. 2019;131(33): 11651–11657. https://doi.org/10.1002/ange.201906137
Xu C., Su Y., Tan L., Liu Z., Zhang J., Chen S., Jiang S. P. Electrodeposited PtCo and PtMn electrocatalysts for methanol and ethanol electrooxidation of direct alcohol fuel cells. Electrochimica Acta. 2009;54(26): 6322–6326. https://doi.org/10.1016/j.electacta.2009.05.088
Kepenienė V., Tamašauskaitė-Tamašiūnaitė L., Jablonskienė J., Vaičiūnienė J., Kondrotas R., Juškėnas R., Norkus E. Investigation of graphene supported platinum-cobalt nanocomposites as electrocatalysts for ethanol pxidation. Journal of The Electrochemical Society. 2014;161(14): F1354–F1359. https://doi.org/10.1149/05901.0217ecst
Mondal A., De A., Datta J. Selective methodology for developing PtCo NPs and performance screening for energy efficient electro-catalysis in direct ethanol fuel cell. International Journal of Hydrogen Energy. 2019;44(21): 10996–11011. https://doi.org/10.1016/j.ijhydene.2019.02.146
Zhai X., Wang P., Wang K., Li J., Pang X., Wang X., Li Z. Facile synthesis of PtCo nanowires with enhanced electrocatalytic performance for ethanol oxidation reaction. Ionics. 2020;26(6): 3091–3097. https://doi.org/10.1007/s11581-019-03419-1
Mauer D., Belenov S., Guterman V., … Safronenko O. Gram-scale synthesis of CoO/C as base for PtCo/C high-performance catalysts for the oxygen reduction reaction. Catalysts. 2021;11(12): 1539–1558. https://doi.org/10.3390/catal11121539
Langford J. I., Wilson A. J. C. Scherrer after sixty years: a survey and some new results in the determination of crystallite size. Journal of Applied Crystallography. 1978;11(2): 102–103. https://doi.org/10.1107/S0021889878012844
Guo J. W., Zhao T. S., Prabhuram J., Chen R., Wong C.W. Preparation and characterization of a PtRu/C nanocatalyst for direct methanol fuel cells. Electrochimica Acta. 2005;51(4): 754–763. https://doi.org/10.1016/j.electacta.2005.05.056
Jenkins R., Snyder R. L. Introduction to X-Ray powder diffractometry. John Wiley & Sons; 1996. 432 p.
Favilla P. C., Acosta J. J., Schvezov C. E., Sercovich D. J., Collet-Lacos J. R. Size control of carbon-supported platinum nanoparticles made using polyol method for low temperature fuel cells. Chemical Engineering Science. 2013;101: 27–34. https://doi.org/10.1016/j.ces.2013.05.067
Hu S., Wang Z., Chen H., Wang S., Li X., Zhang X., Shen P. K. Ultrathin PtCo nanorod assemblies with self-optimized surface for oxygen reduction reaction. Journal of Electroanalytical Chemistry. 2020;870, 114194–114201. https://doi.org/10.1016/j.jelechem.2020.114194
Huang T., Zhang D., Xue L., Cai W.-B., Yu A. A facile method to synthesize well-dispersed PtRuMoOx and PtRuWOx nanoparticles and their electrocatalytic activities for methanol oxidation. Journal of Power Sources. 2009;192(2): 285–290. https://doi.org/10.1016/j.jpowsour.2009.03.037
Kuo C.-W., Lu I-T., Chang L.-C., … Lee J.-F. Surface modification of commercial PtRu nanoparticles for methanol electro-oxidation. Journal of Power Sources. 2013;240: 122–130. https://doi.org/10.1016/j.jpowsour.2013.04.001
Rudi S., Cui C., Gan L., Strasser P. Comparative study of the electrocatalytically active surface Aareas (ECSAs) of Pt alloy nanoparticles evaluated by Hupd and CO-stripping voltammetry. Electrocatalysis. 2014;5: 408–418. https://doi.org/10.1007/s12678-014-0205-2
Van der Vliet D. F., Wang C., Li D., … Stamenkovic V. R. Unique electrochemical adsorption properties of Pt-skin surfaces. Angewandte Chemie International Edition. 2012;51(3): 3139–3142. https://doi.org/10.1002/anie.201107668
de la Fuente J. L. G., Rojas S., Martínez-Huerta M. V., Terreros P., Peña M. A., Fierro J. L. G. Functionalization of carbon support and its influence on the electrocatalytic behaviour of Pt/C in H2 and CO electrooxidation. Carbon. 2006;44: 1919–1929. https://doi.org/10.1016/j.carbon.2006.02.009
Travitsky N., Ripenbein T., Golodnitsky D., Rosenberg Y., Burshtein L., Peled E. Pt-, PtNi- and PtCo-supported catalysts for oxygen reduction in PEM fuel cells. Journal of Power Sources. 2006;161: 782–789. https://doi.org/10.1016/j.jpowsour.2006.05.035
Li X., Liu Y., Zhu J., Tsiakaras P., Shen P. K. Enhanced oxygen reduction and methanol oxidation reaction over self-assembled Pt-M (M = Co, Ni) nanoflowers. Journal of Colloid and Interface Science. 2022;607: 1411–1423. https://doi.org/10.1016/j.jcis.2021.09.060
Yang H. Platinum-based electrocatalysts with core-shell nanostructures. Angewandte Chemie International Edition. 2011;50(12): 2674. https://doi.org/10.1002/anie.201005868
Paulus U. A., Wokaun A., Scherer G. G., Schmidt T. J., Stamenković V., Marković N. M., Ross P. N. Oxygen reduction on high surface area Ptbased alloy catalysts in comparison to well defined smooth bulk alloy electrodes. Electrochimica Acta. 2002;47(22-23): 3787. https://doi.org/10.1016/s0013-4686(02)00349-3
Xing Z., Li J., Wang S., Su C., Jin H. Structure engineering of PtCu3/C catalyst from disordered to ordered intermetallic compound with heat-treatment for the methanol electrooxidation reaction. Nano Research. 2022;15: 3866–3871. https://doi.org/10.1007/s12274-021-3993-8
Petrii O. A. Pt–Ru electrocatalysts for fuel cells: a representative review. Journal of Solid-State Electrochemistry. 2008;12(5): 609–642. https://doi.org/10.1007/s10008-007-0500-4
Tolmachev Y. V., Petrii O. A. Pt–Ru electrocatalysts for fuel cells: developments in the last decade. Journal of Solid-State Electrochemistry. 2017;21: 613–639. https://doi.org/10.1007/s10008-016-3382-5
Castagna R. M., Sieben J. M., Alvarez A. E., Duarte M. M. E. Electrooxidation of ethanol and glycerol on carbon supported PtCu nanoparticles. International Journal of Hydrogen Energy. 2019;44: 5970–5982. https://doi.org/10.1016/j.ijhydene.2019.01.090
Fang B., Feng L. PtCo-NC catalyst derived from the pyrolysis of Pt-incorporated ZIF-67 for alcohols fuel electrooxidation. Acta Physico-Chimica Sinica. 2020;36(7): 1905023. https://doi.org/10.3866/PKU.WHXB201905023
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