Synthesis and properties of nanosized ZnO/wood composite

  • Elena V. Tomina Voronezh State University of Forestry and Technologies named after G. F. Morozov, 8 Timiryazeva ul., Voronezh 394087, Russian Federation; Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation https://orcid.org/0000-0002-5222-0756
  • Anna A. Pavlenko Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation https://orcid.org/0000-0003-4899-609X
  • Aleksandr I. Dmitrenkov Voronezh State University of Forestry and Technologies named after G. F. Morozov, 8 Timiryazeva ul., Voronezh 394087, Russian Federation https://orcid.org/0000-0001-9296-1762
  • Sofiya A. Neminushchaya Voronezh State University of Forestry and Technologies named after G. F. Morozov, 8 Timiryazeva ul., Voronezh 394087, Russian Federation https://orcid.org/0000-0003-2203-3324
Keywords: Zinc oxide, Sol-gel synthesis, Nanoparticles, Silver birch wood (Bétula péndula), Impregnation, Modification

Abstract

The aim of the study was to synthesise a ZnO/silver birch wood (Bétula péndula) nanocomposite and evaluate its physical and mechanical properties in comparison with an unmodified natural polymer.
Using the sol-gel method, we synthesised almost spherical impurity-free zinc oxide nanoparticles with a predominant particle size of about 20 nm. Amorphous hydrated Zn(OH)2 was impregnated into the wood material at the gel formation stage. It resulted in the reaction of zinc hydroxide decomposition with the formation of ZnO nanoparticles in the wood as a nanoreactor.
The hydrophobic properties of the surface of ZnO/silver birch wood nanocomposite improved significantly (the contact angle of wetting doubled). Its moisture and water resistance decreased (2-5 times and 30%, respectively). The nanocomposite also showed less swelling in the radial (8-10 times) and tangential (2.6-10 times) directions in comparison with natural wood.

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Author Biographies

Elena V. Tomina, Voronezh State University of Forestry and Technologies named after G. F. Morozov, 8 Timiryazeva ul., Voronezh 394087, Russian Federation; Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

DSc in Chemistry, Associate
Professor, Head of the Department of Chemistry, Morozov Voronezh State University of Forestry
and Technologies, Voronezh, Russian Federation;
e-mail: tomina-e-v@yandex

Anna A. Pavlenko, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

1st year master’s degree
student, Voronezh State University, Voronezh,
Russian Federation; e-mail: pavlenko-a-a@mail.ru

Aleksandr I. Dmitrenkov, Voronezh State University of Forestry and Technologies named after G. F. Morozov, 8 Timiryazeva ul., Voronezh 394087, Russian Federation

PhD in Technical
Sciences, Morozov Voronezh State University of
Forestry and Technologies, Voronezh, Russian
Federation; e-mail: dmitrenkov2109@mail.ru

Sofiya A. Neminushchaya, Voronezh State University of Forestry and Technologies named after G. F. Morozov, 8 Timiryazeva ul., Voronezh 394087, Russian Federation

student, Morozov
Voronezh State University of Forestry and
Technologies, Voronezh, Russian Federation;
e-mail: nem.sofi@bk.ru

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Published
2021-11-24
How to Cite
Tomina, E. V., Pavlenko, A. A., Dmitrenkov, A. I., & Neminushchaya, S. A. (2021). Synthesis and properties of nanosized ZnO/wood composite. Condensed Matter and Interphases, 23(4), 578-584. https://doi.org/10.17308/kcmf.2021.23/3677
Section
Original articles