The Effect of Certain Complex Chemostimulators and Modifi ers on InP Thermal Oxidation

Keywords: indium phosphide, nanoscale fi lms, chemostimulated oxidation, chemostimulator, modifi er, modifi cation of composition and properties.

Abstract

It is advisable to control characteristics and rate of formation of nanoscale fi lms on InP by introducing chemostimulators, modifi ers, or both simultaneously during the thermal oxidation of semiconductors. The chemostimulating effect of the compounds is determined by their transit role as oxygen transmitters or their catalytic function. Modifi ers can affect the composition, surface morphology, structure, and properties of the fi lm without changing the fi lm growth rate. The effect of chemostimulators and modifi ers on a single process of fi lm synthesis with the desired properties was assumed to be
productive. Purpose: Establishment of the effect of certain complex chemostimulators and modifi ers on the kinetics, growth mechanism, and properties of complex oxide fi lms on InP in the nanoscale thickness range. The object of the study was indium phosphide FIE-1A orientation (100). SnO2/InP and (40 % Co3O4+60 % MnO2)/InP heterostructures with a layer thickness of ~ 30 nm were formed by magnetron sputtering. Sulphate was deposited through the aerosol phase, followed by air drying and annealing at 200 °C for 30 min for the formation of the Bi2(SO4)3/InP heterostructures. SnO2/InP and InP samples were thermally oxidized under the infl uence of AlPO4 and Bi2(SO4)3, respectively, introduced into the gas phase in the temperature range 490-570 °C in an oxygen stream for 60 min. The thickness of the
fi lms was controlled by laser and spectral ellipsometry and their phase and elemental composition were established by XRD and Auger electron spectroscopy, respectively. For the determination of the electrophysical properties of the films, the contacts were sprayed with aluminium and the resistivity was determined. The fundamental role of the physicochemical nature of the chemostimulator, its ability to transit interactions and the renewability of oxide forms in the process of InP thermal oxidation was established. The introduction of phosphate groups from AlPO4 into thermal oxide fi lms, with or without the deposition of SnO2 on the surface, led to the fi lm resistance similar to that for the oxidation of SnO2/InP heterostructures without the additional introduction of phosphates and was 8.5·107 Ohm·cm. Bi2(SO4)3, being a modifi er of the composition and properties of the fi lms, did not have a signifi cant
chemostimulating effect. Films grown under its infl uence had a semiconductor characteristics (r ~ 106 Ohm·cm). The most effective was a 40 % Co3O4+ 60 % MnO2 complex chemostimulator, which determined the accelerated (up to 70 %) formation of fi lm by the catalytic-transit mechanism (up to 70 %), being a part of the synthesized fi lms and capable of purposefully modifying their properties by varying the content of components in it (XRD, SE).

 

 

 

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Author Biographies

Irina Ya. Mittova, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

DSc in Chemistry, Professor,
Professor of Department of Materials Science and
Industry of Nanosystems, Voronezh State University,
Voronezh, Russian Federation; e-mail: imittova@
mail.ru.

Boris V. Sladkopevtsev, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

PhD in Chemistry, Associate
Professor of Department of Materials Science and
Industry of Nanosystems, Voronezh State University,
Voronezh, Russian Federation; e-mail: dp-kmins@yandex.ru.

Natalya A. Ilyasova, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

MSc student of the Department
of Materials Science and Industry of Nanosystems,
Voronezh State University, Voronezh, Russian
Federation; e-mail: Ilyasova_1997@mail.ru.

Elena V. Tomina, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

DSc in Chemistry, Associate
Professor, Associate Professor of Department of
Materials Science and Industry of Nanosystems,
Voronezh State University, Voronezh, Russian
Federation; e-mail: tomina-ev@yandex.ru.

Aleksey I. Dontsov, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation; Voronezh State Technical University, 14, Moskovskij pr., Voronezh 394026, Russian Federation

PhD in Physics and Mathematics,
Associate Professor of the Department of Materials
Science and Industry of Nanosystems, Voronezh State
University, Associate Professor of the Department of
Physics, Voronezh State Technical University,
Voronezh, Russian Federation

Olga S. Tarasova, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

MSc student of the Department
of Materials Science and Industry of Nanosystems,
Voronezh State University, Voronezh, Russian
Federation; e-mail: tarasova_os96@mail.ru.

Published
2020-06-25
How to Cite
Mittova, I. Y., Sladkopevtsev, B. V., Ilyasova, N. A., Tomina, E. V., Dontsov, A. I., & Tarasova, O. S. (2020). The Effect of Certain Complex Chemostimulators and Modifi ers on InP Thermal Oxidation. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 22(2), 245-256. https://doi.org/10.17308/kcmf.2020.22/2851
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