Substances and the transformations they undergo: basic concepts
Abstract
We formulated the specific features for the notions of substances and transformation of substances. A substance is a set of interacting particles characterised by the following parameters 1) composition, or the type and ratio of amounts of particles that form the substances, 2) the energy of their interactions, 3) their structure and, finally, 4) the size of particles (dispersion). Transformations of substances occur when these properties change. Such processes are called chemical reactions. To control the transformation of a substance from the thermodynamic point of view, we need to evaluate: 1. The possibility of spontaneous processes (without energy consumption). 2. The thermal effect of the chemical reaction. 3. The equilibrium
composition of the reaction medium.
We solved these problems using a mathematical model based on the improved notions (substance, energy, work, supersaturation) and the known laws of thermodynamics.
Downloads
References
Zlomanov V. P., Kazin P. E., Yatsenko A. A., Rumyantsev E. V. Brief Dictionary of Basic Chemical Concepts. St. Petersburg: Lan’ Publ.; 2020. 52 p. (In Russ.)
Voronin G. F. Fundamentals of thermodynamics. Moscow: Moscow State University Publ.; 1987. 192 p. (In Russ.)
Eremin V. V., Kargov S. I., Uspenskaya I. A., Kuzmenko N. E., Lunin V. V. Fundamentals of physical chemistry; Textbook Part 1. Theory. 2nd ed. revised and additional. Moscow: BINOM Publ.; 2013. 320 p. (In Russ.)
Gorshkov V. I., Kuznetsov I. A. Fundamentals of physical chemistry. 3rd ed. revised and additional. Moscow: BINOM. Publ.; 2006. 407 p. (In Russ.)
Tamm M. E., Tretyakov Yu. D. Inorganic chemistry. T. 1. Physical and chemical foundations of inorganic chemistry. Moscow: Akademiya Publ.; 2012. 240 p. (In Russ.)
Copyright (c) 2022 Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases
This work is licensed under a Creative Commons Attribution 4.0 International License.