COLD FUSION OF SILICON CARBIDE IN SiO2-CNT COLLOIDAL NANOSYSTEM

  • Dmitry A. Zhukalin
  • Andrey V. Tuchin
  • Dmitry L. Goloshchapov
  • Larisa A. Bityutskaya
  • Frank Roessner
Keywords: nanosystem, carbon nanotubes, silicon dioxide, electronic structure, density functional theory, charge, interface, nanocomposite, silicon carbide.

Abstract

Mechanisms and conditions of the formation of self-organized structures in colloid nanosystem
aerosil — carbon nanotubes (SiO2-CNT) were studied using numerical and natural experiments.
Within the framework of cap/body CNT model we identified two mechanism of interaction of CNT
with SiO2: covalent and Van-der-Waals. Covalent interactions resulted in the formation of self-organized
stem structures with diameter 250—300 nm and length ~4 μm; van-der-Waals interactions
resulted in the formation of spherical agregates with the diameter ~2 μm. X-ray diffraction analysis
of the obtained nanostructures revealed formation of the silicon carbide phase at room temperature.

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Author Biographies

Dmitry A. Zhukalin

post graduate student, Department
of Physics of Semiconductors and Microelectronics,
Voronezh State University; ph.: +7 (951) 5685250, e-mail:
d.zhukalin@mail.ru

Andrey V. Tuchin

post graduate student, Department
of Physics of Semiconductors and Microelectronics, Voronezh
State University; ph.: +7 (908) 1485775, e-mail: a.tuchin@bk.ru

Dmitry L. Goloshchapov

Cand. Sci. (Phys.-Math.),
Chief Engineer, Senior Researcher, Department of Solid
State Physic and Nanostructures, Voronezh State University;
ph.: +7 (905) 0531234, e-mail: goloshchapovdl@gmail.com

Larisa A. Bityutskaya

Cand. Sci. (Chem.), Associate
Professor, Department of Physics of Semiconductors and
Microelectronics, Voronezh State University; ph.: +7 (473)2208481, e-mail: me144@phys.vsu.ru

Frank Roessner

Dr. Sci. (Chem.), Professor of Industrial
Chemistry Department, Carl von Ossietzky University
of Oldenburg; ph. +49 (441) 7983355, e-mail: frank.roessner@uni-oldenburg.de

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Published
2014-12-25
How to Cite
Zhukalin, D. A., Tuchin, A. V., Goloshchapov, D. L., Bityutskaya, L. A., & Roessner, F. (2014). COLD FUSION OF SILICON CARBIDE IN SiO2-CNT COLLOIDAL NANOSYSTEM. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 16(4), 431-438. Retrieved from https://journals.vsu.ru/kcmf/article/view/857
Section
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