Theoretical and experimental investigation on ADT organic semiconductor in different solvents
Abstract
The purpose of this work is to investigate experimental and theoretical methods for the properties of (ADTs) organic semiconductors. The effect of solvent on optical and electrical on Anthradithiophene (ADT) characteristics was investigated. The optoelectronic properties associated with experimental work consists of bandgap energy, Tauc plot, transparency, electrical and optical conductance and dielectric properties calculated. For theoretical calculations, firstly, HOMO and LUMO have been used for the computation of the bandgap energy. The average bandgap energy between HOMO and LUMO is found to be 2.84 eV by using five basis sets in gas phases. After that, the FTIR has been elucidated. In addition, to determine the functional group, and determined the important region did not take place absorption. In general, this region did not
occur absorption which is around between 1650 cm-1 and 3200 cm-1 by using five basis sets. The UV-Vis spectroscopy was elucidated. Furthermore, to determine the energy band-gap, the average energy band gap was found to be 2.59 eV, and it was determined the correct transition type. The ADT molecule exhibited the indirect allowed transition.
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