Optical and magnetic properties of orthoferrite NdFeO3 nanomaterials synthesized by simple co-precipitation method

Фам Ти Хонг  Зуен; Ань Тьен Нгуен

doi:10.17308/kcmf.2021.23/3680

Фам Ти Хонг Зуен Университет Тху Дау Мот, Тху Дау Мот, провинция Биньзыонг, 590000, Вьетнам https://orcid.org/0000-0002-7350-0634
Ань Тьен Нгуен Педагогический университет Хошимина 700000 Хошимин, Вьетнам https://orcid.org/0000-0002-4396-0349

DOI: https://doi.org/10.17308/kcmf.2021.23/3680

Ключевые слова: NdFeO3, наноматериалы, совместное осаждение, оптические и магнитные свойства

Аннотация

В работе описан процесс синтеза наноматериалов (размер частиц от 20 до 40 нм) на основе ортоферрита NdFeO₃методом совместного осаждения посредством гидролиза катионов Nd(III) и Fe(III) в горячей воде с 5 % раствором NaOH в качестве осаждающего реактива. Однофазный NdFeO₃ был получен в результате кальцинации порошка непосредственно после отжига при температуре 700, 800 и 900 °C в течение часа. При комнатной температуре наблюдалось сильное поглощение излучения в ультрафиолетовом и видимом диапазоне (l = 200–400 и 400–600 нм),
а также низкое значение ширины запрещённой зоны (E_g = 2.2÷2.5 эВ). Полученные наноматериалы на основе NdFeO₃проявляют свойства магнитотвердых ферромагнетиков с высокой коэрцитивной силой (Hc = 600–1600 Э).

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Биографии авторов

Фам Ти Хонг Зуен, Университет Тху Дау Мот, Тху Дау Мот, провинция Биньзыонг, 590000, Вьетнам

магистр х. н., преподаватель
Института прикладных технологий, Университет
Тху Дау Мот, провинция Биньзыонг, Вьетнам;
e‑mail: duyenpth@tdmu.edu.vn

Ань Тьен Нгуен, Педагогический университет Хошимина 700000 Хошимин, Вьетнам

к. х. н., доцент, заведующий
кафедрой общей и неорганической химии, Педагогический университет Хошимина, Вьетнам; email:
tienna@hcmue.edu.vn

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