Phase equilibria in the Cu2SnSe3–Sb2Se3–Se system

  • Elnara N. Ismailova Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan https://orcid.org/0000-0002-1327-1753
  • Leyla F. Mashadiyeva Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan https://orcid.org/0000-0003-2357-6195
  • Ikhtiyar B. Bakhtiyarly Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan https://orcid.org/0000-0002-7765-0672
  • Mahammad B. Babanly Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan https://orcid.org/0000-0001-5962-3710
Keywords: Phase diagram, Liquidus surface, Copper-antimony-tin selenides

Abstract

    Complex copper-tin and copper-antimony chalcogenides are of great interest for the development of new environmentally friendly and inexpensive thermoelectric materials. Recently, these compounds have been drawing more interest due to the possibility of increasing their thermoelectric performance with various cationic and anionic substitutions. In this article, we continued the study of multi-component systems based on the copper chalcogenides and presented the results of the study of phase equilibria in the Cu2SnSe3–Sb2Se3–Se system. The study was conducted using differential thermal analysis and powder X-ray diffraction.
       Based on the experimental data, a projection of the liquidus surface and three polythermal cross sections of the phase diagram were plotted. We determined the regions of primary crystallisation of the phases and the nature and temperatures of non-variant and monovariant equilibria.
        It was established that the liquidus surface consisted of two primary crystallisation regions based on Cu2SnSe3 and Sb2Se3 phases. The primary crystallisation region of elementary selenium was degenerate. A large immiscibility region of two liquid phases was found in the system.

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Author Biographies

Elnara N. Ismailova, Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan

PhD student, Researcher,
Institute of Catalysis and Inorganic Chemistry of the
National Academy of Sciences of Azerbaijan (Baku,
Azerbaijan).

Leyla F. Mashadiyeva, Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan

PhD in Chemistry, Senior
Researcher, Institute of Catalysis and Inorganic
Chemistry of the National Academy of Sciences of
Azerbaijan (Baku, Azerbaijan).

Ikhtiyar B. Bakhtiyarly, Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan

Dr. Sci. (Chem.), Professor,
Head of laboratory, Institute of Catalysis and Inorganic
Chemistry of the National Academy of Sciences of
Azerbaijan (Baku, Azerbaijan).

Mahammad B. Babanly, Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan

Dr. Sci. (Chem.), Professor,
Associate Member of the Azerbaijan National Academy
of Sciences, Executive Director of the Institute of
Catalysis and Inorganic Chemistry, Azerbaijan
National Academy of Sciences (Baku, Azerbaijan).

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Published
2023-03-09
How to Cite
Ismailova, E. N., Mashadiyeva, L. F., Bakhtiyarly, I. B., & Babanly, M. B. (2023). Phase equilibria in the Cu2SnSe3–Sb2Se3–Se system. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 25(1), 47-54. https://doi.org/10.17308/kcmf.2023.25/10973
Section
Original articles

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