Phase equilibria in the MnTе–MnGa2Te4–MnIn2Te4 system

Faig M. Mammadov; Samira Z. Imamaliyeva; Yasin İ. Jafarov; Ikhtiyar B. Bakhtiyarly; Mahammad B. Babanly

doi:10.17308/kcmf.2022.24/9856

Faig M. Mammadov Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan https://orcid.org/0000-0003-3317-7438
Samira Z. Imamaliyeva Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan https://orcid.org/0000-0001-8193-2122
Yasin İ. Jafarov Baku State University, 23 Z. Khalilova str., Baku Az1148, Azerbaijan https://orcid.org/0000-0002-6597-2252
Ikhtiyar B. Bakhtiyarly Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan https://orcid.org/0000-0002-7765-0672
Mahammad B. Babanly Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan https://orcid.org/0000-0001-5962-3710

DOI: https://doi.org/10.17308/kcmf.2022.24/9856

Keywords: Manganese-gallium telluride, Manganese-indium telluride, Phase diagram, Liquidus surface, Solid solutions, Magnetic materials

Abstract

A family of compounds with the general formula АВ₂Х₄ (А – Mn, Fe, Co, Ni; B – Ga, In, Sb, Bi; X – S, Se, Te) and complex phases of variable compositions based on them are among promising functional materials with thermoelectric, photoelectric, optical, and magnetic properties. In this article, we continued the study of multi-component systems basd on the chalcogenides of transition metals and presented the results of the study of phase equilibria in the MnTе–MnGa₂Te₄–MnIn₂Te₄ system using differential thermal analysis and X-ray phase analysis.
Based on the experimental results, we built the polythermal cross sections MnTe–MnGaInTe₄ and MnGa₂Te₄–[A] (where [A] is a biphasic alloy of the 2MnTe–MnIn₂Te₄ side system of the 50.0 mol% MnIn₂Te₄ composition) as well as an isothermal section of a phase diagram at 800 K and a projection of the liquidus surface. It was established that the liquidus consists of the fields of primary crystallisation of 4 phases: 1 – Mn-ht; 2 – phases based on various modifications of MnTe; 3 – g₁; 4 – g₂. We also identified types and coordinates of non-variant and monovariant equilibria.
Based on triple compounds (MnGa₂Te₄, MnIn₂Te₄), we determined wide regions of solid solutions that are of particular interest as magnetic materials.

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Author Biographies

Faig M. Mammadov, Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan

PhD (Chem.), Assistance
Professor, Institute of Catalysis and Inorganic
Chemistry, Azerbaijan National Academy of Sciences
(Baku, Azerbaijan).

Samira Z. Imamaliyeva, Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan

PhD (Chem.), Assistance
Professor, Institute of Catalysis and Inorganic
Chemistry, Azerbaijan National Academy of Sciences
(Baku, Azerbaijan).

Yasin İ. Jafarov, Baku State University, 23 Z. Khalilova str., Baku Az1148, Azerbaijan

Dr. Sci. (Chem.), Assistance
Professor, Baku State University (Baku, Azerbaijan).

Ikhtiyar B. Bakhtiyarly, Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan

Dr. Sci. (Chem.), Professor,
Laboratory Manager Institute of Catalysis and
Inorganic Chemistry, Azerbaijan National Academy of
Sciences (Baku, Azerbaijan).

Mahammad B. Babanly, Institute of Catalysis and Inorganic Chemistry n.a. M. Nagiyev of the Azerbaijan National Academy of Sciences, 113 H. Javid av., Baku Az1143, Azerbaijan

Dr. Sci. (Chem.), Professor,
Associate Member of the Azerbaijan National Academy
of Sciences, Executive Director of the Institute of
Catalysis and Inorganic Chemistry, Azerbaijan
National Academy of Sciences (Baku, Azerbaijan).

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Phase equilibria in the MnTе–MnGa2Te4–MnIn2Te4 system

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