Фазы со слоистыми (AB) и «дефектными» (A2B3) структурами в системах AIII– BVI. Часть 2. Фазовые диаграммы и подходы к некоторым задачам воспроизводимого синтеза в системах AIII–BVI. Обзор
Аннотация
В работе проводится анализ фазовых диаграмм систем AIII – BVI и фазовых равновесий с участием кристаллических соединений, образующихся в этих системах. Детально обсуждается место на T-x-диаграмме каждой твердой бинарной фазы – прежде всего, относящихся к семействам моно- и сескви- сульфидов и селенидов алюминия, галлия и индия. При наличии необходимых данных проанализированы и области гомогенности этих фаз. Для полиморфных (или близких к ним) превращений описан характер происходящих структурных превращений и проанализирована температурная устойчивость различных модификаций близкого состава. На примерах нескольких систем показано, как изменяя условия эксперимента, можно воспроизводимо получать соединения с требуемой структурой (даже для разных политипов структур с очень близким строением отдельных слоев) и требуемым составом (в т. ч., и в пределах областей гомогенности фаз). Рассматриваются различные способы воспроизводимого неорганического синтеза с учетом особенностей фазовой диаграммы и фазовых равновесий. В заключении анализируются актуальные и частично до сих пор нерешенные вопросы, касающиеся особенностей соединений A2IIIB3VI и A1IIIB1VI
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