The influence of acid activation of bentonite in the composition of a bipolar membrane on the characteristics of the electrodialysis conversion of sodium sulphate

Keywords: Electrodialysis, Bipolar membrane, Acid activation, Bentonite, Sodium sulphate, Acid, Alkali

Abstract

       The effect on the characteristics of the electrodialysis process of the acid activation of bentonite included in the cationexchange layer of an experimental bipolar membrane obtained by applying a liquid LF-4SK cation-exchange layer containing bentonite particles onto an anion-exchange membrane-substrate MA-41 was studied.
         Acid activation of bentonite was carried out with nitric acid (C = 1 and 4 mol/dm3) for 6 hours at temperatures of 20 and 90 °C. The conversion of sodium sulphate (C = 0.5 mol/dm3) was carried out in a six-section electrodialysis apparatus with experimental bipolar membranes containing bentonite in its original form and after acid activation. It has been shown that the addition of bentonite treated with nitric acid (C = 4 mol/dm3, t = 90 °C, t = 6 h) to the cation-exchange layer of a bipolar membrane leads to an increase in productivity, current efficiency and a decrease in energy costs compared to a membrane containing bentonite in its original form.
         Experimental bipolar membranes made on the basis of MA-41 and a liquid sulphonic cation exchanger containing acidactivated bentonite clays make it possible to obtain an acid and alkali performance  omparable to that of the MB-3 bipolar membrane.

Downloads

Download data is not yet available.

Author Biographies

Sabukhi I. Niftaliev, Voronezh State University of Engineering Technologies, 19 Revolutsii pr., Voronezh 394036, Russian Federation

Dr. Sci. (Chem.), Professor,
Head of Department of Inorganic Chemistry and
Chemical Technology, Voronezh State University of
Engineering Technologies (Voronezh, Russian
Federation)

Olga A. Kozaderova, Voronezh State University of Engineering Technologies, 19 Revolutsii pr., Voronezh 394036, Russian Federation

Dr. Sci. (Chem.), Professor at
the Department of Inorganic Chemistry and Chemical
Technology, Voronezh State University of Engineering
Technologies (Voronezh, Russian Federation)

Ksenia B. Kim, Voronezh State University of Engineering Technologies, 19 Revolutsii pr., Voronezh 394036, Russian Federation

Cand. Sci. (Chem.), Associate
Professor at the Department of Inorganic Chemistry
and Chemical Technology, Voronezh State University
of Engineering Technologies (Voronezh, Russian
Federation)

Petr E. Belousov, Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry of the Russian Academy of Sciences, 35 Staromonetny per., Moscow 119017, Russian Federation

Cand. Sci. (Geology and
Mineralogy), Senior Researcher, Institute of Geology
of Ore Deposits, Petrography, Mineralogy, and
Geochemistry of the Russian Academy of Sciences
(Moscow, Russian Federation)

Victoria V. Krupskaya, Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry of the Russian Academy of Sciences, 35 Staromonetny per., Moscow 119017, Russian Federation

Cand. Sci. (Geology and
Mineralogy), Senior Researcher, Institute of Geology
of Ore Deposits, Petrography, Mineralogy, and
Geochemistry of the Russian Academy of Sciences
(Moscow, Russian Federation)

Anna V. Timkova, Voronezh State University of Engineering Technologies, 19 Revolutsii pr., Voronezh 394036, Russian Federation

postgraduate student,
Department of Inorganic Chemistry and Chemical
Technology, Voronezh State University of Engineering
Technologies (Voronezh, Russian Federation)

References

Melnikov S. S., Mugtamov O. A., Zabolotsky V. I. Study of electrodialysis concentration process of inorganic acids and salts for the two-stage conversion of salts into acids utilizing bipolar electrodialysis. Separation and Purification Technology. 2020;235: 116198–116208. https://doi.org/10.1016/j.seppur.2019.116198

Wiśniewski J., Wiśniewska G., Winnicki T. Application of bipolar electrodialysis to the recovery of acids and bases from water solutions. Desalination. 2004;169(1): 11–20. https://doi.org/10.1016/j.desal.2004.08.003

Kozaderova O. A., Niftaliyev S. I., Kim K. B. Application of bipolar membranes MB-2 modified by chromium (III) hydroxide for sodium sulfate conversion process. ChemChemTech. 2019;62 (3): 30–36. (In Russ., abstract in Eng.). https://doi.org/10.6060/ivkkt201962fp.5811

Öner M. R., Kanca A., Ata O. N., Yapıcı S., Yaylalı N. A. Bipolar membrane electrodialysis for mixed salt water treatment: Evaluation of parameters on process performance. Journal of Environmental Chemical Engineering. 2021;9(4): 105750–105763. https://doi.org/10.1016/j.jece.2021.105750

Niftaliev S., Kozaderova O., Kim K. Application of bipolar electrodialysis with modified membranes for the purification of chromic wastewater from galvanic production. Ecology and Industry of Russia. 2021;25(10): 4–9. (In Russ., abstract in Eng.) https://doi.org/ 10.18412/1816-0395-2021-10-4-9

Purcelli J. Electrodialysis with bipolar membranes: principles, optimization, and application. Russian Journal of Electrochemistry. 2002;38: 919–926. https://doi.org/10.1023/A:1016882216287

Zabolotskii V. I., Utin S. V., Lebedev K. A., Vasilenko P. A., Shel’deshov N. V. Study of pH correction process of chloride-bicarbonate dilute solutions by electrodialysis with bipolar membranes. Russian Journal of Electrochemistry. 2012;48(7): 767–772. https://doi.org/10.1134/S1023193512070130

Kovalev N. V., Karpenko T. V., Sheldeshov N. V., Zabolotsky V. I. Preparation and electrochemical properties of heterogeneous bipolar membranes with a catalyst for the water dissociation reaction. Membranes and Membrane Technologies. 2021;3: 231–244. https://doi.org/10.1134/S251775162104003X

Mel’nikov S. S., Shapovalova O. V., Shel’deshov N. V., Zabolotsky V. I. Effect of d-metal hydroxides on water dissociation in bipolar membranes. Petroleum Chemistry. 2011;51: 577–584. https://doi.org/10.1134/S0965544111070097

Xue Y.-H., Fu R.-Q., Fu Yan-xun, Xu T.-W. Fundamental studies on the intermediate layer of a bipolar membrane. V. Effect of silver halide and its dope in gelatin on water dissociation at the interface of a bipolar membrane. Journal of Colloid and Interface Science. 2006;298: 313–320. https://doi.org/10.1016/j.jcis.2005.11.049

Liu Y., Chen J., Chen R., Zhou T., Ke C., Chen X. Effects of multi-walled carbon nanotubes on bipolar membrane properties. Mater. Chem. Phys. 2018;203: 259–265. https://doi.org/10.1016/j.matchemphys.2017.09.068

Manohar M., Das A. K., Shahi V. K. Efficient bipolar membrane with functionalized graphene oxide interfacial layer for water splitting and converting salt into acid/base by electrodialysis. Industrial and. Engineering Chemistry Resseach. 2018;57: 1129–1136. https://doi.org/10.1021/acs.iecr.7b03885

Martínez R. J., Farrell J. Water splitting activity of oxygen-containing groups in graphene oxide catalyst in bipolar membranes. Computational and Theoretical Chemistry. 2019;1164: 112556. https://doi.org/10.1016/j.comptc.2019.112556

Simons R. Water splitting in ion exchange membranes. Electrochimica Acta. 1985;30(3): 275-282. https://doi.org/10.1016/0013-4686(85)80184-5

Kozaderova O. A. Electrochemical characterization of an MB-2 bipolar membrane modified by nanosized chromium(III) hydroxide. Nanotechnologies in Russia. 2018;13(9-10): 508–515. https://doi.org/10.1134/S1995078018050075

Cheng G., Zhao Y., Li W., Zhang J., Wang X., Dong C. Performance enhancement of bipolar membranes odified by Fe complex catalyst. Journal of Membrane Science. 2019;589: 117243. https://doi.org/10.1016/j.memsci.2019.117243

Kang M.-S., Choi Y.-J., Lee H.-J., Moon S.-H. Effects of inorganic substances on water splitting in ion-exchange membranes; I. Electrochemical characteristics of ion-exchange membranes coated with iron hydroxide/oxide and

ilica sol. Journal Colloid and Interface Science. 2003;273 (2): 523–532. https://doi.org/10.1016/j.jcis.2004.01.050

Kang M.-S., Choi Y.-J., Lee H.-J., Moon S.-H. Effects of inorganic substances on water splitting in ion-exchange membranes. II. Optimal contents of inorganic substances in preparing bipolar membranes. Journal of Colloid and Interface Science. 2004;273: 533–539. https://doi.org/10.1016/j.jcis.2004.01.051

Eswaraswamy B., Suhag A., Goel P., Mandal P., Chattopadhyay S. Potential of montmorillonite nanoclay as water dissociation catalyst at the interface of bipolar membrane. Separation and Purification Technology. 2022;295: 121257–121268. https://doi.org/10.1016/j.seppur.2022.121257

Kozaderova O. A., Kim K. B., Belousov P. E., Timkova A. V., Niftaliev S. I. Electrodialysis of a sodium sulphate solution with experimental bentonitemodified bipolar membranes. Condensed Matter and Interphases. 2021;23(4): 518–528. https://doi.org/10.17308/kcmf.2021.23/3670

Peng F., Penga S., Huang С., Xu T. Modifying bipolar membranes with palygorskite and FeCl3. Journal of Membrane Science. 2008;322: 122–127. https://doi.org/10.1016/j.memsci.2008.05.027

Lin J., Jiang B., Zhan Y. Effect of pre-treatment of bentonite with sodium and calcium ions on phosphate adsorption onto zirconium-modified bentonite. Journal of Environmental Management. 2018;217: 183–195. https://doi.org/10.1016/j.jenvman.2018.03.079

Masindi V. , Ramakokovhu M. M. The performance of thermally activated and vibratory ball milled South African bentonite clay for the removal of chromium ions from aqueous solution. Materials Today: Proceedings. 2021;38 (2): 964–974. https://doi.org/10.1016/j.matpr.2020.05.490

Komadel P. Acid activated clays: Materials in continuous demand. Applied Clay Science. 2016;131: 84–99. https://doi.org/10.1016/j.clay.2016.05.001

Atamanova O. V. , Tikhomirova E. I. , Kasymbekov Zh. K., Podoksenov A. A. Improving the sorption ability of modified bentonite during wastewater treatment by means of its activation. Water and ecology: problems and solutions. Water and Ecology: Problems and Solutions. 2020;1(81): 3–12. (In Russ., abstract in Eng.). https://doi.org/10.23968/2305-3488.2020.25.1.3-12

Krupskaya V., Novikova L., Tyupina E., Belousov P., Dorzhieva O., Zakusin S., Kim K., Roessner F., Badetti E., Brunelli A., Belchinskaya L. The influence of acid modification on the structure of montmorillonites and surface properties of bentonites. Applied Clay Science. 2019;172: 1–10. https://doi.org/10.1016/j.clay.2019.02.001

Niftaliev S. I., Kozaderova O. A., Kim K. B., Belousov P. E. Timkova A. V., Golovkov I. A. Obtaining bentonite-modified bipolar ion-exchange membranes and study of their electrochemical characteristics. Proceedings of the Voronezh State University of Engineering Technologies. 2021;83(3): 216–225. (In Russ., abstract in Eng.). https://doi.org/10.20914/2310-1202-2021-3-216-225

Zabolotsky V. I., Berezina N. P., Nikonenko V. V., Shudrenko A. A. The evolution of membranous technologies on the base of electrodialysis method in Russia. Science of Kuban.2010;3: 4–10. (In Russ., abstract in Eng.). Available at: https://www.elibrary.ru/item.asp?id=23764497

Membrane properties. Available at: http://www.ralex.eu/Membrany/Uvod.aspx

Timofeeva M. N., Panchenko V. N., Gil A., Vicente M. A. Effect of nitric acid modification of montmorillonite clay on synthesis of solketal from glycerol and acetone. Catalysis Communications. 2017; 90: 65–69. https://doi.org/10.1016/j.catcom.2016.11.020

Published
2022-11-01
How to Cite
Niftaliev, S. I., Kozaderova, O. A., Kim, K. B., Belousov, P. E., Krupskaya, V. V., & Timkova, A. V. (2022). The influence of acid activation of bentonite in the composition of a bipolar membrane on the characteristics of the electrodialysis conversion of sodium sulphate. Condensed Matter and Interphases, 24(4), 504-510. https://doi.org/10.17308/kcmf.2022.24/10554
Section
Original articles

Most read articles by the same author(s)