Фазовые диаграммы систем диоксида циркония с оксидами иттрия и скандия
Аннотация
Проанализированы литературные данные по исследованию фазовых равновесий в системах диоксида циркония с оксидами иттрия и скандия. Приведены вероятные схемы низкотемпературных фазовых равновесий в системах ZrO2–Y2O3 и ZrO2–Sc2O3 с учетом третьего закона термодинамики.
Табулированы координаты нонвариантных превращений в этих системах. Признаком неравновесных состояний является наблюдение бездиффузионных процессов упорядочения твердых растворов. Методом модифицированной криоскопии рассчитаны коэффициенты распределения оксидов скандия и иттрия при кристаллизации расплава ZrO2.
Обсуждены возможности существования набора упорядоченных фаз в системе ZrO2–Y2O3 и размытого фазового перехода в кубической модификации диоксида циркония.
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