Физико-химическое исследование процессов дегидратации гидратов b-циклодекстринов
Аннотация
Синтезированы гидраты b-циклодекстрина состава b-CD·nH2O (n = 11.9-0.9).
Полученные соединения исследованы методом рентгенофазового анализа (РФА), который выявил переход от моноклинной элементарной ячейки к орторомбической с уменьшением содержания воды в образцах. Давление насыщенного пара воды гидратов b-CD·nH2O (n = 10.9–7.0) измерено методом статической тензиметрии с мембранными нуль-манометрами в широком температурном интервале (293–384 К) в условиях квази-постоянного состава гидрата. Измеренное давление пара увеличивается пропорционально росту содержания воды в образцах гидрата.
Экспериментальные данные, приведенные к единому составу b-CD·1H2O, были аппроксимированы уравнением ln p(1/T), из которого рассчитаны термодинамические параметры (DпрHT° и DпрST° ) процесса дегидратации гидрата b-циклодекстрина. Полученная информация была использована для оценки энергий связи молекул воды с каркасом b-CD
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