Mass spectrometry of complex compound of bis-thiourea-lead (II) chloride
Abstract
Complex compounds of lead salts and thiourea are of interest due to the possibility of their practical application as precursors in the deposition of metal sulphide films. It is relevant to establish the relationship between the composition and structure of the initial complex compounds and the structure of the sulphides formed as a result of their thermal destruction. This paper presents the results of studying the complex compounds formed in an aqueous solution of lead chloride and thiourea.
The structure of the complex compounds was determined by matrix-assisted laser desorption/ionisation mass spectrometry. The mass spectrometry data confirmed the formation of the [Pb((NH2)2CS)2Cl2] complex in the solution, which is a precursor in the deposition of PbS films. It was demonstrated that mass spectrometry fragmentation of the molecular ion of the [Pb((NH2)2CS)2Cl2] compound leads to the formation of a lead sulphide ion.
The obtained data confirm the formation of the lead-sulphur bonds in the inner sphere of the complex compound, which are fragments of the crystal structure of the prospective sulphide formed during the thermolysis of the complex.
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