Chromatographic approaches to food quality control by chemical compo-sition
Abstract
The article provides an overview of chromatographic methods, which, when used comprehensively, ensure food quality control and safety. It considers gas chromatography methods that allow analysing volatile components in products using a flame ionization detector, an electron capture detector, and mass-selective detectors (GC-FID, GC-ECD, GC-MS, and GC-MS/MS). The article provides a list of analytes that can be detected by high performance liquid chromatography in combination with refractometric, spectrometric, and mass selective detectors (HPLC-RMD, HPLC-UV, HPLC-SPD, HPLC-MS, and HPLC-MS/MS). The study showed how ion chromatography and capillary electrophoresis with electrochemical detectors (IC-ECD, CE-ECD) can be used to detect ionogenic compounds. It highlighted the importance of thin layer chromatography (TLC) in combination with optical digital colour recording devices in the qualitative and quantitative analysis of contaminants in food products. Since it has been established that micro- and nanoplastics have a negative impact on human health, it is very important to detect these particles in food products. This task can be solved by using gel permeation chromatography (GPC) and hydrodynamic chromatography (HDC), as well as the method of field-flaw fractionation (FFF).
It was shown that the GC-MS method is now becoming a priority instrumental method used in accredited analytical laboratories to identify impurities of contaminants in agricultural products. The pyrolytic GC-MS method is promising in this regard. The pyrolytic cell does not require the transfer of a solid sample into a solution for its analysis.
The paper considers extraction and sorption methods for the preparation of samples for chromatographic analysis. A variety of liquid-liquid extraction (LLE) and solid-phase extraction (SPE.) methods are most commonly used. Recently, the QuEChERS method has been developed and widely implemented. The overview is primarily based on the papers dedicated to chromatography and related separation methods published by researchers belonging to Voronezh scientific schools.
Downloads
References
Selemenev V.F., Rudakov O.B. Voro-nezhskie nauchny`e shkoly` po xromato-graficheskim i drugim rodstvenny`m metodam. Analitika. 2023; 13(3): 226-230. https://doi.org/10.22184/2227-572X.2023.13.3.226.230 (In Russ.)
Rudakov O.B., Ry`bakova E.V. Khromatografiya i my`. K 150-letiyu so dnya rozhdeniya M.S. Czveta. Khimiya, fizika i mexanika materialov. 2022; 2(33): 108-123. (In Russ.)
Nasledie M.S. Czveta v trudax vo-ronezhskix ximikov: V 2 tomax / V.F. Sel-emenev, O.B. Rudakov, D.L. Kotova et al. V. 1. Voronezh:Izdatel`sko-poligraficheskij centr "Nauchnaya kniga", 2021. 358 p. (In Russ.)
Nasledie M.S. Czveta v trudax vo-ronezhskix ximikov: V 2 tomax / V.F. Sel-emenev, O. B. Rudakov, D. L. Kotova et al. V. 2. Voronezh: Izdatel`sko-poligraficheskij centr "Nauchnaya kniga", 2021. 330 p. (In Russ.)
Selemenev V.F., Rudakova L.V., Rudakov O.B. Lipidomika. Voronezh: Nauchnaya kniga, 2023, 316 p. (In Russ.)
Selemenev V.F., Rudakova L.V., Rudakov O.B. Vitaminy` kak ob``ekty` pishhevoj ximii i farmakologii. Voronezh: Izdatel`sko-poligraficheskij centr "Nauchnaya kniga", 2022, 212 p. (In Russ.)
Rudakov O.B., Korol`kova N.V., Polyanskij K.K. Texnoximicheskij kontrol` v texnologii zhirov i zhirozamen-itelej. Sankt-Peterburg: Izdatel`stvo "Lan`", 2020, 576 p. (In Russ.)
Selemenev V.F., Rudakova L.V., Rudakov O.B. Fosfolipidy` na fone prirod-ny`x matricz. Voronezh: Izdatel`sko-poligraficheskij centr «Nauchnaya kniga», 2020, 318 p. (In Russ.)
Dolgonosov A. M., Rudakov O. B., Prudkovskij A. G. Kolonochnaya analitich-eskaya xromatografiya: praktika, teoriya, modelirovanie. Sankt-Peterburg, Izda-tel`stvo "Lan`", 2015, 468 p. (In Russ.)
Rudakova L.V., Rudakov O.B. In-formacionny`e texnologii v analiticheskom kontrole biologicheski aktivny`x veshhestv. Sankt-Peterburg: Izdatel`stvo "Lan`", 2015, 468 p. (In Russ.)
Polyanskij K.K., Rudakov O.B., Podporinova G.K. Natural`ny`e i is-kusstvenny`e podslastiteli. Svojstva i e`kspertiza kac hestva. Moskva: OOO "DeLi print", 2009, 252 p. (In Russ.)
Rudakov O.B., Ponomarev A.N., Polyanskij K.K., Lyubar` A.V. Zhiry`. Xi-micheskij sostav i e`kspertiza kachestva. M.: OOO "DeLi print", 2005, 312 p. (In Russ.)
Rudakov O.B., Selemenev V.F., Vostrov I.A. Sputnik xromatografista. Metody` zhidkostnoj xromatografii. Voro-nezh, 2004, 526 p. (In Russ.)
Rudakov O.B., Rudakova L.V. Aminokislotny`j analiz belkov myasa. My-asny`e texnologii. 2020; 2(206): 29-35. (In Russ.)
Rudakov O.B., Rudakova L.V., Pol-yanskij K.K. Analiticheskij kontrol` kon-taminantov v pishhevoj produkcii – gar-antiya ee kachestva i bezopasnosti. Inno-vacionnoe predprinimatel`stvo: social`no-e`konomicheskie i marketingovy`e aspek-ty`: materialy` Mezhdunarodnoj nauchno-prakticheskoj konferencii, Voronezh, 28-29 aprelya 2017 goda Voronezh: Izdatel`sko-poligraficheskij centr "Nauchnaya kniga", 2017: 362-368. (In Russ.)
Yashin A., Yashin Ya., Cher-nousova N. Opredelenie summarnogo soderzhaniya zhirorastvorimy`x antioksi-dantov v molochny`x, ry`bny`x, myasny`x produktax i rastitel`ny`x maslax. Analitika. 2012; 5(6):16-21. (In Russ.)
Yashin Ya.I. Yashin A.Ya. Analit-icheskaya xromatografiya. Metody`, appa-ratura, primenenie. Uspexi ximii. 2006; 75(4): 366-379. (In Russ.)
Lavruxina O.I., Amelin V.G., Kish L.K. Opredelenie ostatochny`x kolichestv pesticidov v ob``ektax okruzhayushhej sredy` i pishhevy`x produktax. Obzor. Xi-micheskaya bezopasnost`. 2022; 6(2): 81-116. (In Russ.)
Amelin V.G., Nikeshina T.B., Tret`yakov A.V. Identifikaciya i opredele-nie pesticidov i policiklicheskix aro-maticheskix uglevodorodov v vode i pish-hevy`x produktax metodom xromato-mass-spektrometrii. Zhurnal analiticheskoj ximii. 2011; 66(10): 1036-1041. (In Russ.)
Bol`shakov D.S., Kochetova A.N., Podkolzin I.V. Sovremenny`e metody` opredeleniya podlinnosti pishhevy`x produktov.Trudy` Federal`nogo centra ox-rany` zdorov`ya zhivotny`x. 2020; 17: 257-299. (In Russ.)
Borisova T. Kontrol` kachestva produktov pitaniya i pishhevogo sy`r`ya. Resheniya Shimadzu. Analitika. 2016; 3(28): 64-71. (In Russ.)
Vinogradova N. I. Tonkoslojnaya xromatografiya. M-vo vnutrennix del Ros-sijskoj Federacii, Moskovskij un-t. Mos-kva: MosU MVD Rossii, 2008, 23 p. (In Russ.)
Paczovskij A.P. Sovremenny`e dos-tizheniya v oblasti tonkoslojnoj xromato-grafii. Mir izmerenij. 2013; 1: 36-40. (In Russ.)
Sy`chev K.S. Podgotovka proby` dlya gazovoj i zhidkostnoj xromatografii. Moskva. Iz-vo Integrated BioSeparation Solutions OU, 2019. 128 p. (In Russ.)
Rudakov O.B., Rudakova L.V., Pol-yanskij K.K. Mesto xromatografii v kontro-le kachestva i bezopasnosti sy`r`ya i sel`skoxozyajstvennoj produkcii. Proizvod-stvo i pererabotka sel`skoxozyajstvennoj produkcii: menedzhment kachestva i be-zopasnosti: Materialy` mezhdunarodnoj nauchno-prakticheskoj konferencii, posvyashhennoj 25-letiyu fakul`teta texnologii i tovarovedeniya Voronezh-skogo gosudarstvennogo agrarnogo univer-siteta imeni imperatora Petra I, Voronezh, 07–09 noyabrya 2018 goda. Tom Chast` II. Voronezh: Voronezhskij gosudarstvenny`j agrarny`j universitet im. Imperatora Petra I, 2018; 405-410. (In Russ.)
Rudakov O.B., Selemenev V.F., Rudakova L.V. Nizkotemperaturnoe razdelenie i koncentrirovanie v usloviyax obrazovaniya geterogenny`x sistem (ob-zor), Sorbtsionnye i khromatograficheskie protsessy. 2019; 19(4): 418-433. https://doi.org/10.17308/sorpchrom.2019.19/780. (In Russ.)
Rudakov O.B., Selemenev V.F., Rudakova L.V., Podolina E.A. Xromato-graficheskie i e`kstrakcionny`e svojstva acetonitrila i ego smesej s vodoj. Sorbtsionnye i khromatograficheskie protsessy`. 2018; 18(4): 458-478. https://doi.org/10.17308/
sorpchrom.2018.18/554 (In Russ.)
Stolyarov B. V. Gazoxromato-graficheskij parofazny`j analiz reakcion-ny`x sistem: dissertaciya… doktora xi-micheskix nauk. Sankt-Peterburg, 2000. 397 p. (In Russ.)
Rudakov O.B, Rodionova N.S., Bo-charova O.N. Sovremennoe sostoyanie kolichestvennogo kontrolya uglevodov v pishhevy`x produktax metodami vy`sokoe`ffektivnoj zhidkostnoj xromato-grafii (obzor). Xranenie i pererabotka sel`xozsy`r`ya, 1999; 2: 52-56. (In Russ.)
Rudakov O.B., Boev A.I., Nikitina S.Yu. Vozmozhnosti piroliticheskoj xroma-tografii v identifikacii molochnogo zhira. Xranenie i pererabotka sel`xozsy`r`ya. 2002; 3: 49-52. (In Russ.)
Rudakov O.B., Xoroxordin A.M., Rudakov Ya.O., Xoroxordina E.A. Prime-nenie piroliticheskoj xromato-mass-spektrometrii v kontrole kachestva stroi-tel`ny`x polimerov i kompozitov. Stroi-tel`ny`e materialy`. 2022; 8: 65-69. https://doi.org/
31659/0585-430X-2022-805-8-65-69 (In Russ.)
Rudakov O.B., Rudakova L.V. Bisfenol A: s chem ego edyat? Pererabotka moloka. 2019; 6(236): 24-26. https://doi.org/10.33465/2222-5455-2019-6-24-26 (In Russ.)
Rudakov O.B., Rudakova L.V. PE`T-upakovka na vzglyad ximika-analitika. Pererabotka moloka. 2019; 8(238): 36-41. https://doi.org/10.33465/2222-5455-2019-8-36-40 (In Russ.)
Rudakov O.B., Rudakova L.V. Na-nochasticy iz plastika – aktual`ny`j kon-taminant pishhevoj produkcii. Myasny`e texnologii. 2019; 10(202): 48-51. https://doi.org/10.33465/2308-2941-2019-10-48-51 (In Russ.)
Rudakov O.B., Rudakova L.V., Abbud M. Cifrovaya czvetometriya v far-macevticheskom analize i kontrole produk-tov pitaniya. Analitika. 2014; 14(1): 58-67. (In Russ.)
Rudakov O.B., Rudakova L.V. Obe-sogeny` – ser`eznaya problema pishhevoj industrii. Myasny`e texnologii, 2024; 2: 38-41. (In Russ.)
