Formation of plasmon-exciton nanostructures based on quantum dots and metal nanoparticles with a nonlinear optical response

Keywords: Nonlinear refraction, Nonlinear absorption, Quantum dot, Ag2S, Zn0.5Cd0.5S, Plasmonic nanoparticle, Z-scan

Abstract

    The establishment of the conditions for the formation of nanostructures with plasmon-exciton interaction based onquantum dots and plasmonic nanoparticles that provide unique nonlinear optical properties is an urgent task. The study demonstrates the formation of plasmon-exciton nanostructures based on hydrophilic colloidal Zn0.5Cd0.5S, Ag2S quantum dots and metal nanoparticles.
     Transmission electron microscopy and optical absorption and luminescence spectroscopy were used to substantiate the formation of plasmon-exciton hybrid nanostructures. The phase composition of the studied samples was determined by X-ray diffraction. The results obtained using ARLX’TRA diffractometer (Switzerland) indicated a cubic crystal structure (F43m) of synthesised Zn0.5Cd0.5S quantum dots and monoclinic (P21/C) crystal lattice of Ag2S. Transmission electron microscopy revealed that plasmonic nanoparticles are adsorption centres for quantum dots. The average sizes of the studied samples were determined: colloidal Ag2S quantum dots (2.6 nm), Zn0.5Cd0.5S(2.0 nm) and metal nanoparticles: silver
nanospheres (10 nm) and gold nanorods (4x25 nm). The transformation of the extinction spectra of the light and the luminescence quenching of quantum dots have been established in mixtures of quantum dots and plasmonic nanoparticles.
    The nonlinear optical parameters of the studied samples were determined using the Z-scanning method at wavelengths of 355 and 532 nm in the field of nanosecond laser pulses. The conditions for the formation of hybrid nanostructures that provide an increase of the coefficient of nonlinear absorption of laser pulses (355 and 532 nm) up to 9 times with a duration of 10 ns due to the reverse saturable absorption occurring due to cascade two-quantum transitions in the intrinsic and local states of colloidal quantum dots and the suppression of nonlinear refraction, were determined.
    The observed changes were explained by the manifestation of the Purcell effect on the states of quantum dots in the presence of nanoresonators (gold nanorods and silver nanospheres). The results of these studies create new opportunities for the development of original systems for controlling the intensity of laser radiation, as well as quantum sensors of a new generation

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Author Biographies

Andrey I. Zvyagin, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

Cand. Sci. (Phys.–Math.),
Lecturer, Department of Optics and Spectroscopy,
Voronezh State University (Voronezh, Russian
Federation).

Tamara A. Chevychelova, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

postgraduate student,
Department of Optics and Spectroscopy, Voronezh
State University (Voronezh, Russian Federation)

Aleksey S. Perepelitsa, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

Cand. Sci. (Phys.–Math.),
Associate Professor at the Department of Optics and
Spectroscopy, Voronezh State University (Voronezh,
Russian Federation)

Mikhail S. Smirnov, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

Dr. Sci. (Phys.–Math.), Associate
Professor, Department of Optics and Spectroscopy,
Voronezh State University (Voronezh, Russian
Federation).

Oleg V. Ovchinnikov, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

Dr. Sci. (Phys.–Math.), Full
Professor, Dean of the Faculty of Physics, Head of the
Department of Optics and Spectroscopy, Voronezh
State University (Voronezh, Russian Federation)

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Published
2023-07-07
How to Cite
Zvyagin, A. I., Chevychelova, T. A., Perepelitsa, A. S., Smirnov, M. S., & Ovchinnikov, O. V. (2023). Formation of plasmon-exciton nanostructures based on quantum dots and metal nanoparticles with a nonlinear optical response. Kondensirovannye Sredy I Mezhfaznye Granitsy = Condensed Matter and Interphases, 25(3), 350-358. https://doi.org/10.17308/kcmf.2023.25/11258
Section
Original articles

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