Engineering of biomimetic composite dental materials based on nanocrystalline hydroxyapatite and light-curing adhesive

Pavel V. Seredin; Dmitry L. Goloshchapov; Asaad. A. H. AlZubaidi; Vladimir M. Kashkarov; Nikita S. Buylov; Yury A. Ippolitov; Jitraporn (Pimm) Vongsvivut

doi:10.17308/kcmf.2022.24/9858

Pavel V. Seredin Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation https://orcid.org/0000-0002-6724-0063
Dmitry L. Goloshchapov Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation https://orcid.org/0000-0002-1400-2870
Asaad. A. H. AlZubaidi Medical Instruments Techniques Engineering Department, Technical College of Engineering, Al-Bayan University, Baghdad, Iraq https://orcid.org/0000-0003-4852-0825
Vladimir M. Kashkarov Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation https://orcid.org/0000-0001-9460-9244
Nikita S. Buylov Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation https://orcid.org/0000-0003-1793-4400
Yury A. Ippolitov Department of Pediatric Dentistry with Orthodontia, Voronezh State Medical University, 11 Studentcheskaya str., Voronezh 394006, Russian Federation https://orcid.org/0000-0001-9922-137X
Jitraporn (Pimm) Vongsvivut ANSTO-Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 3168, Australia https://orcid.org/0000-0003-0699-3464

DOI: https://doi.org/10.17308/kcmf.2022.24/9858

Keywords: Biomimetic strategies, Nanodentology, Calcium hydroxyapatite, Adhesives

Abstract

With the use of light-curing Bis-GMA (Bis-phenol-А glycidylmethacrylate) adhesive and nanocrystalline carbonatesubstituted calcium hydroxyapatite (nano-сHAp), corresponding by an aggregate set of characteristics to the apatite of human enamel and dentin obtained from the biogenic source of calcium – egg’s shell of birds biomimetic Bis-GMA/nano-сHAp adhesives were synthesized.
Introduction and distribution of nano-cHAp filler in the adhesive matrix as well as its interaction with molecular groups of the latter one resulted in the change of chemical bonds that was evidenced by the data of Fourier transform infrared (FTIR) spectroscopy. In summary, for the specified nanofiller concentration increased values of Vicker hardnesses (VH) and degree of conversion were attained simultaneously while light curing of Bis-GMA/nano-cHAp adhesive.
This result would provide a considerable influence on the following application of the developed biomimetic adhesives and clinical successes of teeth restoration with the use of these composites

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Author Biographies

Pavel V. Seredin, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

Dr. Sci. (Phys.–Math.), Full
Professor, Chair of Department, Department of Solid
State Physics and Nanostructures, Voronezh State
University (Voronezh, Russian Federation).

Dmitry L. Goloshchapov, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

Cand. Sci. (Phys.–Math.),
Assistant Professor, Department of Solid State Physics
and Nanostructures, Voronezh State University
(Voronezh, Russian Federation).

Asaad. A. H. AlZubaidi, Medical Instruments Techniques Engineering Department, Technical College of Engineering, Al-Bayan University, Baghdad, Iraq

PhD, Lecturer, Medical
Instruments techniques Engineering Department,
Technical College of Engineering, Al-Bayan University
(Baghdad, Iraq)

Vladimir M. Kashkarov, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

Cand. Sci. (Phys.–Math.),
Senior Researcher, Department of Solid State Physic
and Nanostructures, Voronezh State University
(Voronezh, Russian Federation).

Nikita S. Buylov, Voronezh State University, 1 Universitetskaya pl., Voronezh 394018, Russian Federation

Cand. Sci. (Phys.–Math.), Educator,
Department of Solid State Physics and Nanostructures,
Voronezh State University (Voronezh, Russian
Federation).

Yury A. Ippolitov, Department of Pediatric Dentistry with Orthodontia, Voronezh State Medical University, 11 Studentcheskaya str., Voronezh 394006, Russian Federation

Dr. Sci. (Med.), Full Professor,
Head of Dentistry Institute of Postgraduate Medical
Education Department, Voronezh State Medical
University (Voronezh, Russian Federation).

Jitraporn (Pimm) Vongsvivut, ANSTO-Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 3168, Australia

Beamline Scientist,
IR Microspectroscopy, Australian Synchrotron,
Synchrotron Light Source Australia Pty LTD (Melburn,
Australia).

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